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2012 |
2011 |
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479. R. Breslow, “The
Future of Organic Chemistry—an Essay,” in Organic Chemistry—Breakthroughs and Perspectives,
Ding, K. and Dai, L-X, eds., Wiley-VCH, 2012, Weinheim, Germany, p 781-789.
478. L.Cheng, K. G. Abhilash,
and R. Breslow, “Binding and Biomimetic Cleavage of the RNA Poly(U) by
Synthetic Polyimidazoles,” Proc. Natl. Acad. Sci. USA 2012, 109, 12884-12887.
477. H. Vazquez, R.
Skouta, S. Schneebeli, M. Kamenetska, R. Breslow, L. Venkataraman, M. S. Hybertsen,
“Probing the conductance superposition law in single-molecule circuits with
parallel paths,” Nature
Nanotech. 2012, 7, 663-667.
2011
476. R. Breslow,
“Artificial enzymes, cancer chemotherapy, conjugation and nanoelectronics, and
prebiotic chemistry.” Sci. China Chem. 2011, 54, 1803-1814.
475. W. Chen, J. R. Widawsky, H. Vázquez, S. T. Schneebeli, M. S.
Hybertsen, R. Breslow, L.Venkataraman, “Highly Conducting π-conjugated Molecular
Junctions Covalently Bonded To Gold Electrodes.” J. Amer. Chem. Soc. 2011, 133,
17160-17163.
474. R. Breslow, S.
Schneebeli, “Structure-property relationships in molecular wires.” Tetrahedron
2011, 67,
10171-10178.
473. Z.-L.
Cheng, R. Skouta, H. Vazquez, J. R. Widawsky, S. Schneebeli, W. Chen, M.S. Hybertsen,
R. Breslow, L.Venkataraman, “In situ Formation of Highly Conducting, Covalent
Au-C Contacts for Single Molecule Transport.” Nature Nanotech., 2011, 6, 353-357.
472. R. Breslow, “The origin of homochirality in amino acids and
sugars on prebiotic earth.” Tetrahedron Lett. 2011, 52, 4228-4232.
471. S. Schneebeli, M. Kamenetska, Z. Cheng, R.
Skouta, R. A. Friesner, L. Venkataraman, and R. Breslow, “Single-Molecule
Conductance through Multiple π−π-Stacked Benzene Rings Determined with Direct Electrode-to-Benzene
Ring Connections” J. Am. Chem. Soc. 2011, 133, 2136–2139.
2010
470. S. Schneebeli, M. Kamenetska, F. Foss, H.
Vazquez, R. Skouta, M. Hybertsen, L. Venkataraman, and R. Breslow, “The
Electrical Properties of Biphenylenes” Org. Lett. 2010, 12, 4114–4117.
469. Huanyu Zhao and Ronald Breslow, “A mimic of the
pyruvate dehydrogenase complex.” Bioorg. Med. Chem. Lett. 2010, 20,
5973-5975.
468. R. Breslow, “Cyclodextrins,” in Molecular
Encapsulation, Eds. Uso Berinker and Jean-Luc Mieusset, Wiley, Chichester UK,
2010, pp. 43-65.
467. R. Breslow, “The Principles and Reasons for Using Water
as a Solvent for Green Chemistry,” in Green Solvents, Eds. Paul Anastas and
Chao-Jun Li, Wiley-VCH, Weinheim Germany, 2010, pp.1-29.
466. Ronald Breslow and Zhan-Ling Cheng, “L-amino acids
catalyze the formation of an excess of D-glyceraldehyde, and thus of other D sugars,
under credible prebiotic conditions.”
Proc. Natl. Acad. Sci. USA. 2010;
107:5723-5725.
455. Ronald Breslow, Mindy Levine, and Zhen-Ling Cheng, “Imitating
Prebiotic Homochirality on Earth,” Orig. Life Evol. Biosph. 2010, 40, 11-26.
2009 Top
454. T. Dadosh, J.
Sperling, G. W. Bryant, R. Breslow, T. Shegai, M. Dyshel, G. Haran, I.
Bar-Joseph, “Plasmonic Control of
the Shape of the Raman Spectrum of a Single Molecule in a Silver Nanoparticle
Dimer.“ ACS Nano 2009, 3(7), 1988-1994.
453. R. Breslow,
“Nature: a Model System for Chemists,” Wiley Encyclopedia of Chemical Biology
(2009), 3,
277-284.
452. R. Breslow, “Vorinostat”,
Molec.
Intervent. 2009, 9, 114-115.
451. Rachid Skouta,
Sujun Wei, and Ronald Breslow, “High Rates and substrate selectivities in water
by polyvinylimidazoles as transaminase enzyme mimics with hydrophobically bound
pyridoxamine derivatives as coenzyme mimics,” J. Am. Chem. Soc. 2009, 131,
15604-15605.
450. Sujun Wei,
Jianing Wang, Scott Venhuizen, Rachid Skouta and Ronald Breslow, “Dendrimers in
solution can have their remote catalytic groups folded back into the core:
Enantioselective transaminations by dendritic enzyme mimics-II,” Bioorg. Med.
Chem. Lett. 2009, 19, 5543-5546.
449. R. Breslow,
“Reply to Bada: The relevance of meteoritic alpha-methyl amino acids to
prebiotic homochirality,” published Online Proc. Natl. Acad. Sci. USA 30 July 2009.
448. Ronald Breslow
and Zhan-Ling Cheng, “On the origin of terrestrial homochirality for
nucleosides and amino acids,” PNAS 2009, 106, 9144-9146.
447. S. T.
Schneebeli, M. L. Hall, R. Breslow, and R. Friesner, “Quantitative
DFT Modeling of the Enantiomeric Excess for Dioxirane-Catalyzed Epoxidations,” J. Am. Chem. Soc. 2009,131, 3965-3973.
446. R. Breslow, “Biomimetic Chemistry: Biology as an
Inspiration,” J.
Biol. Chem. 2009, 284, 1337 – 1342.
2008
Top
445. Huanyu Zhao,
Frank W. Foss, Jr., and Ronald Breslow, “Artificial Enzymes with Thiazolium and
Imidazolium Coenzyme Mimics,” J. Am. Chem. Soc. 2008, 130, 12590-12591.
444. Breslow, R. (2008), "Biomimetic Catalysis", in
Austin, D. (ed.), Chemical Biology: The role of Chemistry in our fundamental
understanding of Biology, The Biomedical & Life Sciences Collection,
Henry Stewart Talks Ltd, London (online at http://www.hstalks.com/bio)
443. Ronald Breslow and Frank Foss Jr., “Charge transport in
nanoscale aromatic and antiaromatic systems,” J. Phys.: Condens. Matter 2008, 20, 374104.
442. Mindy Levine, Craig S. Kenesky, Shengping Zheng, Jordan
Quinn, and Ronald Breslow, “Synthesis and catalytic properties of diverse
chiral polyamines,” Tetrahedron Lett. 2008, 49, 5746-5750.
441. Mindy Levine, Daniel Mazori and Ronald Breslow,
“Enantioselective Synthesis and Enantiomeric Amplification of Amino Acids under
Prebiotic Conditions.” Org. Lett., 2008, 10, 2433-2436.
2007 Top
440.
Jordan R. Quinn, Frank W. Foss, Jr., Latha Venkataraman, and Ronald Breslow,
“Oxidation Potentials Correlate with Conductivities of Aromatic Molecular
Wires,” J. Am.
Chem. Soc., 2007, 129, 12376-12377.
439.
Ronald Breslow, “A Fifty-Year Perspective on Chemistry in Water,” in Organic Reactions
in Water, Marcus Lindstrom, ed., Blackwell Publishers, Oxford, 2007, pp.
1-28.
438.
Jordan R. Quinn, Frank W. Foss, Jr., Latha Venkataraman, Mark S. Hybersten and
Ronald Breslow, “Single-Molecule Junction Conductance through Diaminoacenes,” J. Am. Chem. Soc.,
2007, 129, 6714-6715.
437.
Ronald Breslow, Sujun Wei, and Craig Kenesky, “Enantioselective Transaminations
by Dendrimeric Enzyme Mimics,” Tetrahedron, 2007, 63, 6317-6321.
436. Subhajit Bandyopadhyay, Wenjun Zhou and
Ronald Breslow, “Isotactic Polyethylenimines Induce Formation of L-Amino Acids
in Transamination,”Org. Lett. 2007, 9, 1009-1012.
435.
Paul A. Marks and Ronald Breslow, “Dimethylsulphoxide to vorinostat:
development of this histone deacetylase inhibitor as an anticancer drug,” Nature Biotech.
2007, 25,
84-90.
434. Ronald Breslow, “The Hydrophobic Effect in Reaction
Mechanism Studies and in Catalysis by Artificial Enzymes,” J. Phys. Org. Chem. 2006, 19, 813-822.
433. Ronald Breslow, Subhajit Bandyopadhyay, Mindy Levine, and
Wenjun Zhou, “Water Exclusion and Enantioselectivity in Catalysis,” ChemBioChem 2006,
7, 1491-1496.
432. Ronald Breslow and Mindy Levine, “Amplification of
enantiomeric concentrations under credible prebiotic conditions,” Proc. Nat. Acad.
Sci. USA 2006, 103,
12979-12980.
431.
Ronald Breslow and Mindy Levine, "Partial transfer of enantioselective
chiralities from alpha-methylated amino acids, known to be of meteoritic
origin, into normal amino acids," Tetrahedron Lett. 2006, 47, 1809-1812.
430. Zhenglai Fang and Ronald Breslow, "Metal
Coordination-Directed Hydroxylation of Steroids with a Novel Artificial P-450
Catalyst," Org.
Lett. 2006,
8,
251-254.
429.
Iris W. Tam, Jiaming Yan, and Ronald Breslow; "An 11nm Molecular Wire that
Switches Elechrochemically between and Insulating and a Fully Conjugated
Conducting State," Org. Lett. 2006, 8, 183-185.
428.
Xuefeng Guo, Joshua P. Small, Jennifer E. Klare, Yiliang Wang, Meninder S.
Purewal, Iris W. Tam, Byung Hee Hong, Robert Caldwell, Limin Huang, Stephen
O'Brien, Jiaming Yan, Ronald Breslow, Shalom J. Wind, James, Philip Kim, Colin
Nuckolls, "Covalently Bridging Gaps in Single-Walled Carbon Nanotubes with
Conducting Molecules," Science 2006, 311, 356-359.
2005 Top
427. Christopher Uyeda, Mark Biscoe, Paul LePlae and Ronald
Breslow, "Hydrophobically directed selective reduction of ketones using
amine boranes," Tetrahedron Lett. 2005, 47, 127-130.
426.
Zhenglai Fang and Ronald Breslow, "A Thiolate Ligand on a Cytochrome P-450
Mimic Permits the Use of Simple Environmentally Benign Oxidants for Biomimetic
Steroid Hydroxylation in Water," Biorg. Med. Chem. Lett. 2005, 15, 5463-5466.
425.
Jason J. Chruma, Lei Liu, Wenjun Zhou and Ronald Breslow, "Hydrophobic and
electronic factors in the design of dialkylglycine decarboxylase mimics," Bioorg. Med.
Chem. 13, 5873-5883 (2005).
424.
Mark R. Biscoe and Ronald Breslow, "Oxaziridinium Salts as Hydrophobic
Epoxidation Reagents: Remarkable Hydrophobically-Directed Selectivity in Olefin
Epoxidation," J. Am .Chem. Soc. 127, 10812-10813 (2005).
423.
Lei Liu and Ronald Breslow, "Vitamin B6 Enzyme Models, in "Artificial
Enzymes," R. Breslow, ed., Wiley-VCH, Weinheim, Germany, 2005, pp. 37-62.
422.
R. Breslow, "Artificial Enzymes," in "Artificial Enzymes,"
R. Breslow, ed., Wiley-VCH, Weinheim, Germany, 2005, pp. 1-35.
421.
R. Breslow, ed., "Artificial Enzymes," Wiley-VCH, Weinheim, Germany,
2005.
420.
W. Zhou, N. Yerkes, J. J. Chruma, L. Liu, and R. Breslow, "Chiral
polyamines from reduction of polypeptides: asymmetric pyridoxamine-mediated
transaminations", Bioorg. Med. Chem. Lett. 15. 1351-1355 (2005).
419.
M. R. Biscoe, C. Uyeda, and R. Breslow, "Requirements for Selective
Hydrophobic Acceleration in the Reduction of Ketones", Org. Lett. 6,
4331-4334 (2004).
418.
D. Bong, I. Tam, and R. Breslow, "Oligothiophene Isocyanides for
Platinum-Based Molecular Electronic Applications", J. Amer. Chem. Soc. 126, 11796-11797
(2004).
417.
R. Breslow, "Determining the Geometries of Transition States by Use of
Antihydrophobic Additives in Water," Accts. Chem. Res. 37, 471-478 (2004).
416.
L. Liu and R. Breslow, "Polymeric and dendrimeric pyridoxal enzyme
mimics," Bioorg.
Med. Chem. 12, 3277-3287 (2004).
415.
L. Liu, W. Zhou, J. Chruma, and R. Breslow, "Transamination Reactions with
Multiple Turnovers Catalyzed by Hydrophobic Pyridoxamine Cofactors in the
Presence of Polyethylenimine Polymers," J. Am. Chem. Soc. 126, 8136-8137 (2004).
414.
T. Ito, Y. Fudamoto, A. Fukaya, I. M. Gat-Malureanu, M. I. Larkin, P. L. Russo,
A. Savici, Y. J. Uemura, K. Groves, R. Breslow, K. Hotehama, S. Yamanaka, P.
Kyriakou, M. Rovers, G. M. Luke, K. M. Kojima, "Two-dimensional nature of
superconductivity in the intercalated layered systems LixHfNCl and LixZrNCl:
Muon spin relaxation and magnetization measurements," Phys. Rev. B 69, 134522/1-134522/13
(2004).
2003
Top
413.
R. Breslow, "Polymeric enzyme mimics," Polymer Preprints 44, 480 (2003).
412.
R. Pearman, D. T. Bong, R. Breslow, and G. W. Flynn, "Nanostructured
thiophenes through self-assembly: Toward molecular electronics," Poly. Mat. Sci.
and Engin. 89, 213 (2003).
411.
M. R. Biscoe and R. Breslow, "Hydrophobically Directed Selective Reduction
of Ketones," J. Am. Chem. Soc. 125, 12718-12719 (2003).
410.
M. Leivers, I. Tam, K. Groves, D. Leung, Y. Xie, and R. Breslow, "A
Forbidden Rearrangement," Org. Lett. 5, 3407-3409 (2003).
409.
L. Liu and R. Breslow, "Dendrimeric Pyridoxamine Enzyme Mimics," J. Am. Chem. Soc.
125, 12110-12111 (2003).
408.
W. Zhou, L. Liu, and R. Breslow, "Transamination by Polymeric Enzyme
Mimics," Helv.
Chim. Acta 86, 3560-3567 (2003).
407.
D. Wilson, L. Perlson, and R. Breslow, "Helical Templating of
Oligopeptides by Cyclodextrin Dimers," Bioorg. Med. Chem. 11, 2649-2653 (2003).
2002 Top
406.
S. Moore, J. A. Askew, G. L. Gibson, A. Aborgrein, T. Huckerby, O. M. A.
El-Agnaf, D. Allsop, D. K. Leung, and R. Breslow, "Novel cyclodextrin
dimers and trimers as inhibitors of amyloid peptide aggregation," Neurobiology of
Aging 23, S105 (2002).
405.
L. Liu, M. Rozenman, and R. Breslow, "Hydrophobic Effects on Rates and
Substrate Selectivities in Polymeric Transaminase Mimics," J. Am. Chem. Soc.
124, 12660-12661 (2002).
404.
L. Liu, M. Rozenman, and R. Breslow, "Stereoselectivity in Reactions of
Amino Acids Catalyzed by Pyridoxal Derivatives Carrying Rigidly-Attached
Chirally-Mounted Basic Groups-Transamination, Racemization, Decarboxylation,
Retro-Aldol Reaction, and Aldol Condensations," Bioorg. Med. Chem. 10, 3973-3979 (2002).
403.
J. Yang, B. Gabriele, S. Belvedere, Y. Huang, and R. Breslow, "Catalytic
Oxidations of Steroid Substrates by Artificial Cytochrome P-450 Enzymes," J. Org. Chem.
67, 5057-5067 (2002).
402.
R. Breslow and Z. Fang, "Hydroxylation of Steroids with an Artificial
P-450 Catalyst Bearing Synthetic Cyclophanes as Binding Groups," Tetrahedron Lett.
43, 5197-5200 (2002).
401.
R. Breslow, "Biomimetic Regioselective Template-Directed
Functionalizations: An Update," CHEMTRACTS Org. Chem., 15, 59-68 (2002).
400.
L. Liu and R. Breslow, "A Potent Polymer/Pyridoxamine Enzyme Mimic," J. Am. Chem. Soc.
124, 4978-4979 (2002).
399.
R. Breslow, K. Groves, and M. Uljana Mayer, "Antihydrophobic Cosolvent
Effects for Alkylation Reactions in Water Solution, Particularly Oxygen versus
Carbon Alkylations of Phenoxide Ions," J. Am. Chem. Soc. 124, 3622-3635 (2002).
398.
R. Breslow, J. Yan, and S. Belvedere, "Catalytic Hydoxylation of Steroids
by Cytochrome P-450 Mimics. Hydroxylation at C-9 with Novel Catalysts and
Steroid Substrates," Tetrahedron Lett. 43, 363-365 (2002).
397.
R. Breslow, J. Yang, and J. Yan, "Biomimetic Hydroxylation of Saturated
Carbons with Artificial Cytochrome P-450 Enzymes-Liberating Chemistry from the
Tyranny of Functional Groups," Tetrahedron 58, 653-659 (2002).
2001 Top
396.
P. A. Marks, V. M. Richon, R. Breslow, and R. A. Rifkind, "Histone
Deacetylase Inhibitors as New Cancer Drugs," Curr. Opin. Oncol. 13, 477-483 (2001).
395.
M. Leivers and R. Breslow, "Concerning Two-Metal Cooperativity in Model
Phosphate Hydrolysis," Bioorg. Chem. 29, 345-356 (2001).
394.
S. D. P. Baugh, Z. Yang, D. K. Leung, D. M. Wilson, and R. Breslow, "
Cyclodextrin Dimers as Cleavable Carriers of Photodynamic Sensitizers," J. Am. Chem. Soc.
123, 12488 -12494 (2001).
393.
P. A. Marks, R. A. Rifkind, V. M. Richon, R. Breslow, T. Miller and W. K.
Kelly, "Histone Deacetylases and Cancer: Causes and Therapies," Nature Reviews
Cancer 1, 194-202 (2001).
392.
R. Breslow, "Cyclodextrin Derivatives as Mimics of Enzymes and
Antibodies," Biolog. J. Armenia 53, 117-120 (2001).
391.
S. Belvedere and R. Breslow , "Regioselective Oxidation of Steroids by a
Manganese Porphyrin Carrying Metal Coordinating Groups," Bioorg. Chem.
29, 321-331 (2001).
390.
D. K. Leung, J. H. Atkins, and R. Breslow, "Synthesis and Binding
Properties of Cyclodextrin Trimers," Tetrahedron Lett. 42, 6255-6258 (2001).
389.
L. M. Butler, Y. Webb, D. B. Agus, B. Higgins, T. R. Tolentino, M. C. Kutko, M.
P. LaQuaglia, M. Drobnjak, C. Cordon-Cardo, H. I. Scher, R. Breslow, V. M.
Richon, R. A. Rifkind, and P. A. Marks, "Inhibition of Transformed Cell
Growth and Induction of Cellular Differentiation by Pyroxamide, an Inhibitor of
Histone Deacetylase," Clinical Cancer Research 2001, 7, 962-970 (2001).
388.
L. Liu and R. Breslow, "Selective Racemization in Preference to
Transamination Catalyzed by Pyridoxal Enzyme Analogs," Tetrahedron Lett.
42, 2775-2777 (2001).
2000 Top
387.
R. Breslow, "Biomimetic Selectivity," The Chemical Record 2000, 1,
3-11 (2000).
386.
J. Yang and R. Breslow, "Regioselective Oxidations of Equilenin
Derivatives Catalyzed by a Rhodium (III) Porphyrin Complex&emdash;Contrast
with the Manganese (III) Porphyrin," Tetrahedron Lett. 41, 8063-8067
(2000).
385.
R. Breslow, "Extending Nature,", Proc. Amer. Phil. Soc. 144, 267-274
(2000).
384.
R. Breslow, S. Belvedere, and L. Gershell, "Development of
Cytodifferentiating Agents for Cancer Chemotherapy," Helv. Chim. Acta, 83,
1685-1692 (2000).
383.
N. Nesnas, J. Lou, and R. Breslow, "The Binding of Cocaine to
Cyclodextrins," Bioorg. & Med. Chem. Lett., 10, 1931-1933 (2000).
382.
J. Yang and R. Breslow, "Selective Hydroxylation of a Steroid at C-9 by an
Artificial Cytochrome P-450," Angew. Chem. Int. Ed. 39, 2692-2694 (2000).
381.
R. Breslow, S. Belvedere, L. Gershell, and D. Leung, "The Chelate Effect
in Binding, Catalysis, and Chemotherapy," Pure Appl. Chem. 72, 333-342
(2000).
380.
D. K. Leung, Z. Yang, and R. Breslow, "Selective Disruption of Protein
Aggregation by Cyclodextrin Dimers," Proc. U.S. Natl. Acad. Sci. 97,
5050-5053 (2000).
379.
J.Yan and R. Breslow, "An Enzyme Mimic that Hydrolyzes an Unactivated
Ester with Catalytic Turnover," Tetrahedron Lett. 41, 2059-2062 (2000).
378.
J. Yang, R. Weinberg, and R. Breslow, "The Hydroxylation and Amidation of
Equilenin Acetate Catalyzed by
Chloro[5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato]manganese(III)"
Chem. Commun. 531-532 (2000).
1990 - 1999 Top
377.
A. Ruebner, Z. Yang, D. Leung, and R. Breslow, "A Cyclodextrin Dimer with
a Photocleavable Linker as a Possible Carrier for the Photosensitizer in
Photodynamic Tumor Therapy," Proc. U.S. Natl. Acad. Sci. 96, 14692-14693
(1999).
376.
R. Breslow, "Biomimetic Reactions Directed by Templates and Removable
Tethers," in Templated Organic Synthesis, F. Diederich and P. Stang, eds,
Wiley-VCH, Weinheim, Germany, 1999, chap. 6.
375.
M. S. Finnin, J. R. Donigian, A. Cohen, V. M. Richon, R. A. Rifkind, P. A.
Marks, R. Breslow, and N. A. Pavletich, "Structures of a Histone
Deacetylase Homologue Bound to the TSA and SAHA Inhibitors," Nature 401,
188-193 (1999).
374.
R. Breslow, K. Groves, and M. U. Mayer, "Antihydrophobic Cosolvent Effects
in Organic Displacement Reactions," Org. Lett. 1, 117-120 (1999).
373.
E. Fasella, S. D. Dong, and R. Breslow, "Reversal of Optical Induction in
Transamination by Regioisomeric Bifunctionalized Cyclodextrins," Bioorg.
Med. Chem. 7, 709-714 (1999).
372.
R. Breslow, "Antiaromatic Triplet Ground State Nolecules: Building Blocks
for Organic Magnets," in Magnetic Properties of Organic Materials, P. M.
Lahti, ed., Marcel Dekker, New York, 1999, chap. 3.
371.
Y. Webb, X. Zhou, L. Ngo, V. Cornish, J. Stahl, H. Erdjument-Bromage, P.
Tempst, R. A. Rifkind, P. A. Marks, R. Breslow, and V. M. Richon,
"Photoaffinity Labeling and Mass Spectrometry Identify Ribosomal Protein
S3 as a Potential Target for Hybrid Polar Cytodifferentiation Agents." J.
Biol. Chem., 274, 14280-14287 (1999).
370.
R. Breslow and N. Nesnas, "Burst Kinetics and Turnover in an Esterase
Mimic," Tetrahedron Lett. 40, 3335-3338 (1999).
369.
P. A. Marks, V. M. Richon, R. Breslow, and R. A. Rifkind, "Hybrid polar
inducers of transformed cell differentiation/apoptosis. From the cell to the
clinic," C. R. Acad. Sci. Paris/Life Sciences, 322, 161-165 (1999).
368.
M. Sprecher, R. Breslow, R. Philosof-Oppenheimer, and E. Chavet, "Steroid
Phosphate Esters," Tetrahedron , 55, 5465-5482 (1999).
367.R.
Breslow, F. McCormick, and C. Werner, "A Stable Cyclopentenyl Trication
Derivative," Tetrahedron Lett. 40, 2447-2448 (1999).
366. Y. Webb, L. Ngo, V. M. Richon, R. Breslow, R. Rifkind, and
P. A. Marks, "Identification of a Poetential Target for Hybrid Polar
Cytodifferentiation Agents," Proc. Amer. Assoc. for Cancer Res. 39, 108
(1998).
365.
R. Breslow, K. Groves, and M. U. Mayer, "The Hydrophobic Effect as a
Mechanistic Tool," Pure & Appl. Chem. 70, 1933-1938 (1998).
364.
S. D. Dong and R. Breslow, "Bifunctional Cyclodextrin Metalloenzyme
Mimics," Tetrahedron Lett. 39, 9343-9346 (1998).
363.
D.-Q. Yuan, S. D. Dong, and R. Breslow, "Cyclodextrin-based Class I
Aldolase Enzyme Mimics to Catalyze Crossed Aldol Condensations,"
Tetrahedron Lett. 39, 7673-7676 (1998).
362.
M. Uljana Mayer and R. Breslow, "Antihydrophobic Evidence for the Single
Electron Transfer Mechanism of Nucleophilic Substitution," J. Am. Chem.
Soc,. 120, 9098-9099 (1998).
361.
R. Breslow, "Water as a Solvent for Chemical Reactions," in
"Green Chemistry," P. T. Anastas and T. C. Williamson, eds, Oxford
Press, New York, 1998, chap. 13.
360.
R. Breslow and S. D. Dong, "Biomimetic Reactions Catalyzed by
Cyclodextrins and Their Derivatives," Chem. Rev. 98, 1997-2011 (1998).
359.
R. Breslow, "Studies in Biomimetic Chemistry," Pure & Appl. Chem.
70, 267-270 (1998).
358.
R. Breslow, Bioorganic Chemistry: A Natural and Unnatural Science, J. Chem. Ed.
75, 705-718 (1998).
357.
R. Breslow, B. Gabriele, and J. Yang, "Geometrically Directed Selective
Steroid Hydroxylation with High Turnover by a Fluorinated Artificial Cytochrome
P-450," Tetrahedron Lett. 39, 2887-2890 (1998).
356.
R. Breslow, Z. Yang, R. Ching, G. Trojandt, and F. Odobel, "Sequence
Selective Binding of Peptides by Artificial Receptors in Aqueous
Solution," J. Am. Chem. Soc. 120, 3536-3537 (1998).
355.
V. M. Richon, S. Emiliani, E. Verdin, Y. Webb, R. Breslow, R. A. Rifkind, and
P. A. Marks, "A Class of Hybrid Polar Inducers of Transformed Cell
Differentiation Inhibits Histone Deacetylases," Proc. Natl. Acad. Sci. USA
95, 3003-3007 (1998).
354.
R. Breslow, "Biomimetic Chemistry: a Frontier at the Chemistry/Biology
Interface," Chem. & Biol. 5, R27-28 (1998).
353. R. Breslow, Y. Huang, and J. Yang, "An Artificial
Cyctochrome P450 that Hydroxylates Unactivated Carbons with Regio- and
Stereoselectivity and Useful Catalytic Turnovers," Proc. Natl. Acad. Sci.
USA 94, 11156-11158 (1997).
352.
Z. Yang and R. Breslow, "Very Strong Binding of Lithocholic Acid to
ß-Cyclodextrin," Tetrahedron Lett. 38, 6171-6172 (1997).
351.
M. Rezac and R. Breslow, "A Mutase Mimic with Cobalamin Linked to
Cyclodextrin," Tetrahedron Lett. 38, 5763-5766 (1997).
350.
R. Breslow,"Imitating Antibodies and Enzymes," Proc. Robert A Welch
Foundation 40th Conference on Chem. Res. 40, 1-11 (1997).
349.
R. Breslow, X. Zhang, and Y. Huang, "Selective Catalytic Hydroxylation of
a Steroid by an Artificial Cytochrome P-450 Enzyme," J. Am. Chem. Soc,.
119, 4535-4536 (1997).
348.
R. Breslow, "What will Physical Organic Chemistry Achieve in the 21st
Century," Pure & Appl. Chem. 69, 223-225 (1997).
347.
J. Klicic, Y. Rubin, and R. Breslow, "Approaches to Stable Cyclopropenyl
Anions: tris-1,2,3-p-Nitrophenylcyclopropene," Tetrahedron, 53, 4129-4136
(1997).
346.
R. Xu and R. Breslow, "Triphenylcyclopropenium Bromide," Org. Syn.,
74, 72-75 (1997).
345.
B. Zhang and R. Breslow, "Ester Hydrolysis by a Catalytic Cyclodextrin
Dimer Enzyme Mimic with a Metallobipyridyl Linking Group," J. Am. Chem.
Soc., 119, 1676-1681 (1997).
344.
R. Breslow, "Bifunctional Binding and Catalysis," NATO ASI Ser., Ser.
E, 320, 113-135 (1996).
343.
R. Breslow, X. Zhang, R. Xu, M. Maletic, and R. Merger, "Selective
Catalytic Oxidation of Substrates that Bind to Metalloporphyrin Enzyme Mimics
Carrying Two of Four Cyclodextrin Groups and Related Metallosalens," J.
Am. Chem. Soc, 118, 11678-11679 (1996).
342.
R. Breslow and C. Schmuck, "The Mechanism of Thiazolium Catalysis,"
Tetrahedron Lett. 37, 8241-8242 (1996).
341.R.
Breslow and T. L. Sheppard, "Why Natural DNA is Based on 2'-Deoxyribose,
with 3',5' Phosphodiester Links," Pure & Appl. Chem. 68, 2037-2041
(1996).
340.
T. L. Sheppard and R. C. Breslow, "Selective Binding of RNA, but Not DNA,
by Complementary 2',5'-Linked DNA," J. Am. Chem. Soc., 40, 9810-9811
(1996).
339.
R. Breslow and W. H. Chapman, Jr., "On the Mechanism of Action of
Ribonuclease A: Relevance of Enzymatic Studies with a p-Nitrophenylphosphate Ester and a
Thiophosphate Ester," Proc. Natl. Acd. Sci. USA, 93, 10018-10021 (1996).
338.
R. Breslow and B. Zhang, "Cholesterol Recognition and Binding by
Cyclodextrin Dimers," J. Am. Chem. Soc., 118, 8495-8496 (1996).
337.
R. Breslow, R. Connors, and Z. Zhu, "Mechanistic Studies Using
Antihydrophobic Agents," Pure & Appl. Chem., 68, 1527-1533 (1996).
336.
M. Maletic, H. Wennemers, D. Q. McDonald, R. Breslow, and W. C. Still,
"Selective Binding of Dipeptides L-Phe-D-Pro and D-Phe-L-Pro to
ß-Cyclodextrin," Angew. Chem. Int. Ed. Engl., 35, 1490-1492 (1996)
335.
R. Breslow and C. Schmuck, "Goodness of Fit in Complexes between
Substrates and Ribonuclease Mimics: Effects on Binding, Catalytic Rate
Constants, and Regiochemistry," J. Am. Chem. Soc. 118, 6601-6605 (1996).
334.
R. Breslow, S. D. Dong, Y. Webb, and R. Xu, "Further Studies on the
Buffer-Catalyzed Cleavage and Isomerization of Uridyluridine. Medium and Ionic
Strength Effects on Catalysis by Morpholine, Imidazole, and Acetate Buffers
Help Clarify the Mechanisms Involved and Their Relationship to the Mechanism
Used by the Enzyme Ribonuclease and by a Ribonuclease Mimic," J. Am. Chem.
Soc. 118, 6588-6600 (1996).
333. V. M. Richon, Y. Webb, R. Merger, T. Sheppard, B. Jursic,
L. Ngo, F. Civoli, R. Breslow, R. A. Rifkind, and P. A. Marks, " Second
Generation Hybrid Polar Compounds are Potent Inducers of Transformed Cell
Differentiation," Proc. Natl. Acd. Sci. USA, 93, 5705- 5708 (1996).
332.
R. Breslow and R. Connors, "Antihydrophobic Cosolvent Effects Detect Two
Different Geometries for an SN2 Displacement and the Change to a
Single-Electron Transfer Mechanisms in Related Cases," J. Am. Chem. Soc.
118, 6323-6324 (1996).
331.
R. Breslow, J. Desper, and Y. Huang, "A Selective Intramolecular Aldol
Condensation Directed by a Bifunctional Enzyme Mimic," Tetrahedron Lett.
37, 2541-2544 (1996).
330.
J. Light and R. Breslow, "A Water-soluble Tin Hydride: Tris[3-(2-
methoxyethoxy)propyl]stannane", Org. Synth. 72,199 (1995).
329.
R. Breslow, "Binding and Catalysis with Flexible Locks and Flexible
Keys", Supramolecular Chemistry, 66, 41-47 (1995).
328.
R. Breslow and Z. Zhu, "Quantitative Antihydrophobic Effects as Probes for
Transition State Structures. 2. Diels-Alder Reactions", J. Am. Chem. Soc.
117, 9923-9924 (1995).
327.
R. Breslow and R. V. Connors, "Quantitative Antihydrophobic Effects as
Probes for Transition State Structures. 1. Benzoin Condensation and
Displacement Reactions", J. Am. Chem. Soc. 117, 6601-6602 (1995).
326.
W. H. Chapman, Jr., and R. Breslow, "Selective Hydrolysis of Phosphate
Esters, Nitrophenyl Phosphates and UpU, by Dimeric Zinc Complexes Depends on
the Spacer Length", J. Am. Chem. Soc. 117, 5462-5469 (1995).
325.
R. Breslow, "Studies on Bioorganic Reactions and Mechanisms", in
Organic Reactivity: Physical and Biological Aspects, B. T. Golding, R. J.
Griffin, and H. Maskill, eds., The Royal Society of Chemistry, Cambridge
England, 1995, Special Publication No. 148, pp. 3-24.
324.
R. Breslow, P. J. Duggan, D. Wiedenfeld, and S. T. Waddell, "The Binding
Properties of Cyclophane Dimers", Tetrahedron Lett. 36, 2707- 2710 (1995).
323. R. Breslow, "Biomimetic Chemistry and Artificial
Enzymes: Catalysis by Design", Accts. Chem. Res. 28, 146-153 (1995).
322.
R. Breslow, S. Halfon, and B. Zhang, "Molecular Recognition by
Cyclodextrin Dimers", Tetrahedron, 51, 377-388 (1995).
321.
M. Sprecher, R. Breslow, O. Uziel, and T. M. Link, "Monosubstituted 2,2'-Bipyridines",
OPPI Briefs 26, 696-701 (1994).
320.
J. M. Desper and R. Breslow, "Catalysis of an Intramolecular Aldol
Condensation by Imidazole-Bearing Cyclodextrins", J. Am. Chem. Soc. 116,
12081-12082 (1994).
319.
J. T. Koh, L. Delaude, and R. Breslow, "Geometric Control of a
Pyridoxal-Catalyzed Aldol Condensation", J. Am. Chem. Soc. 116,
11234-11240 (1994).
318.
L. P. Le, A. Keren, G. M. Luke, W. D. Wu, Y. J Uemura, W. S. Jenks, A. Graff,
R. Breslow, P. Dosanjh "mSR Studies in an I2-Doped Phenylenediamine
Polymer", Hyperfine Interactions 85 287-292 (1994).
317. T. L. Sheppard, A. T. Rosenblatt, and R. Breslow,
"Preparation of 2'-O- (b-Cyanoethyl phosphoramidites) of 3'-Deoxycytidine
and 3'- Deoxyguanosine and their Use for Solid-Phase Synthesis of
Oligodeoxynucleotides Containing 2',5'-Phosphodiester Linkages", J. Org.
Chem. 59, 7243-7248 (1994).
316.
R. Breslow, "The Chelate Effect in Binding, Catalysis, and
Chemotherapy", Recl. Trav. Chim. Pays-Bas 113, 493 (1994).
315.
R. Breslow, "Hydrophobic and Antihydrophobic Effects on Organic Reactions
in Aqueous Solution", in Structure and Reactivity in Aqueous Solution, C.
J. Cramer and D. G. Truhlar, eds., American Chemical Society, Washington, D.C.,
1994, pp. 291-302.
314.
R. Breslow and B. Zhang, "Cleavage of Phosphate Esters by a Cyclodextrin
Dimer Catalyst that Binds the Substrates Together with La3+ and Hydrogen
Peroxide", J. Am. Chem. Soc. 116, 7893-7894 (1994).
313.
R. Breslow, "Bifunctional Acid-Base Catalysis by Imidazole Groups in
Enzyme Mimics", J. Mol. Cat. 91, 161-174 (1994).
312.
R. Breslow, "Biomimetic Chemistry", Pure & Appl. Chem. 66, 1573-
1582 (1994).
311.
R. Breslow and R. Kim, "The Thiazolium Catalyzed Benzoin Condensation with
Mild Base Does not Involve a "Dimer" Intermediate", Tetrahedron
Lett. 35, 699-702 (1994).
310.
R. Breslow, "The Correct Use of Partitioning Ratios in the Derivation of
Rate Equations" J. Chem. Ed. 71, 999-1000 (1993).
309.
R. Breslow and A. Graff, "Geometry of Enolization Using a Bifunctional
Cyclodextrin-Based Catalyst" J. Am. Chem. Soc. 115, 10988-10989 (1993).
308.
R. Breslow and R. Xu, "Quantitative Evidence for the Mechanism of RNA
Cleavage by Enzyme Mimics. Cleavage and Isomerization of UpU by Morpholine
Buffers" J. Am. Chem. Soc. 115, 10705-10713(1993).
307.
R. Jin, W. H. Chapman, Jr., A. R. Srinivasan, W. K. Olson, R. Breslow, and K.
J. Breslauer, "Comparative Spectroscopic, Calorimetric, and Computational
Studies of Nucleic Acid Complexes with 2',5"- versus
3',5"-phosphodiester Linkages," Proc. Natl. Acad. Sci. USA 90, 10568-
10572 (1993).
306.
B. Zhang and R. Breslow, "Enthalpic Domination of the Chelate Effect in
Cyclodextrin Dimers" J. Am. Chem. Soc. 115, 9353-9354 (1993).
305.
R. Breslow, "Model Studies Clarify an Enzyme Mechanism" Citation
Classic, Curr. Cont. Physical, Chemical and Earth Sciences 33, 8 (1993). Curr.
Cont. Engineering, Techanology, and Applied Sciences 24, 8 (1993).
304.
R. Breslow, "Bifunctional Binding and Catalysis", Supramol. Chem. 1,
111-118 (1993).
303.
R. Breslow and D. Wiedenfeld, "Quinoline and Acridine Templates in
Selective Steroid Chlorinations", Tetrahedron Lett. 34, 1107-1110 (1993).
302.
R. Breslow, "Kinetics and Mechanism in RNA Cleavage", Proc. Natl.
Acad. Sci. USA 90, 1208-1211 (1993).
301.
R. Breslow and R. Xu, "Recognition and Catalysis in Nucleic Acid
Chemistry", Proc. Natl. Acad. Sci. USA 90, 1201-1207(1993).
300.
R. Breslow, "Molecular Recognition", Proc. Natl. Acad. Sci. USA 90,
1139 (1993).
299.
R. Breslow, "Selective Binding and Catalysis by Cyclodextrins",
Minutes of the Sixth International Symposium on Cyclodextrins, Editions de
Sante, Paris, 625-630 (1992).
298.
R. Breslow, "Bifunctional Binding and Catalysis in Host-Guest
Chemistry", Israel Jour. Chem. 32 , 23-30 (1992).
297.
P. A. Marks, R. A. Rifkind, V. Richon, T. Powell, X. Busquets, L. Leng, H.
Kiyokawa, J. Michaeli, B. Jursic, and R. Breslow, "Hexamethylene
Bisacetamide and Related Agents as Inducers of Differentiation of Transformed
Cells: Mechanism of Action and Potential for Cancer Therapy", Concise
Reviews in Experimental and Clinical Hematology, Martin J. Murphy, Ed.,
AlphaMed Press, Dayton, Ohio, (1992) 91-99.
296.
R. Breslow and S. Halfon, "Quantitative Effects of Antihydrophobic Agents
on Binding Constants and Solubilities in Water", Proc. Natl. Acad. Sci.
USA 89, 6916-6918 (1992).
295.
J. P. Dougherty, C. J. Rizzo, and R. Breslow, "Oligonucleotides That
Contain 2',5" Linkages: Synthesis and Hybridization Properties", J.
Am. Chem. Soc. 114, 6254-6255 (1992).
294.
R. Breslow and T. Link, "Chemical Degradation of Steroid Side Chains.
Efficient Conversion of Cholestanol to Corticosteroid Intermediates",
Tetrahedron Lett. 33, 4145-4148 (1992).
293.
C. J. Rizzo, J. P. Dougherty and R. Breslow, "3'-Deoxy-2'- Phosphoramidates
of Adenosine and 5-Methyluridine Used for the Solid Phase Synthesis of
Unnatural 3'-Deoxy-2',5"-Oligonucleotides", Tetrahedron Lett. 33,
4129-4132 (1992).
292.
R. Breslow and B. Zhang, "Very Fast Ester Hydrolysis by a Cyclodextrin
Dimer with a Catalytic Linking Group", J. Am. Chem. Soc. 114, 5882-5883
(1992).
291.
R. Breslow, "Binding and Catalysis in Water", Supramolecular
Chemistry, 411-428 (1992).
290.
R. Breslow, P. J. Duggan, and J. P. Light , "Cyclodextrin-B12, a Potential
Enzyme-Coenzyme Mimic", J. Am. Chem. Soc. 114, 3982-3983 (1992).
289.
G. A. Crispino and R. Breslow, "Synthesis of Tripyridiniumpropenyl Anions
from Tripyridiniumcyclopropanes and -cyclopropenes" J. Org. Chem. 57,
1849-1855 (1992).
288. R. Breslow, "Oxidation by Remote Functionalization
Methods", in "Comprehensive Organic Synthesis", Barry M. Trost,
ed., vol. 7, 39-53, Pergamon Press, Oxford (1991).
287.
R. Breslow, "How do Imidazole Groups Catalyze the Cleavage of RNA in
Enzyme Models and in Enzymes? Evidence from "Negative
Catalysis"", Accts. Chem. Res. 24, 317-324 (1991).
286.
D. Wiedenfeld and R. Breslow, "Directed Formation of Carbon- Bromine and
Carbon-Sulfur Bonds by Tandem Radical Chain Reactions", J. Am. Chem. Soc.
113, 8977-8978 (1991).
285.
R. Breslow, B. Jursic, Z. F. Yan, E. Friedman, L. Leng, L. Ngo, R. A. Rifkind,
and P. A. Marks, "Potent Cytodifferentiating Agents Related to
Hexamethylenebisacetamide", Proc. Natl. Acad. Sci. USA 88, 5542-5546
(1991).
284.
R. Breslow, "Hydrophobic Effects on Simple Organic Reactions in
Water", Accts. Chem. Res. 24, 159-164 (1991).
283.
R. Breslow and D.-L. Huang, "Effects of Metal Ions, including Mg2+ and
Lanthanides, on the Cleavage of Ribonucleotides and RNA Model Compounds",
Proc. Natl. Acad. Sci. USA 88, 4080-4083 (1991).
282.
R. Breslow and Carmelo J. Rizzo, "Chaotropic Salt Effects in a
Hydrophobically Accelerated Diels-Alder Reaction", J. Am. Chem. Soc. 113,
4340-4341 (1991).
281.
R. Breslow and J. W. Canary, "Rapid Nucleophilic Substitutions on
Cyclopentadienyl Iodide and Bromide", J. Am. Chem. Soc. 113, 3950- 3952
(1991).
280.
R. Breslow, "Enzyme Mimics", Ciba Foundation Symposium 158, 115-127
(1991).
279.
R. Breslow, E. Anslyn, and D.-L. Huang, "Ribonuclease Mimics",
Tetrahedron 47, 2365-2376 (1991).
278.
R. Breslow and G. A. Crispino, "Tripyridylcyclopropene Derivatives and
their Conversion to Hexapyridylbenzene", Tetrahedron Lett. 32, 601-604
(1991).
277.
R. Breslow and S. Chung, "Strong Binding of Ditopic Substrates by a Doubly
Linked Occlusive C1 "Clamshell" as Distinguished from an Aversive C2
"Loveseat" Cyclodextrin Dimer", J. Am. Chem. Soc. 112, 9659-9660
(1990).
276.
P. A. Marks, R. A. Rifkind and R. Breslow, "Induced Differentiation of
Transformed Cells: Mechanism of Action and Application in Cancer Therapy"
in Molecular Basis of Haematopoiesis , L. Sachs, N. G. Abraham, C. Weidemann,
A. S. Levine and G. Konwalinka, eds., Intercept, Ltd., Andlover, Great Britain,
579-586 (1990).
275.
R. Breslow and D.-L. Huang, "A Negative Catalytic Term Requires a Common
Intermediate in the Imidazole Buffer Catalyzed Cleavage and Rearrangement of
Ribodinucleotides", J. Am. Chem. Soc. 112, 9621-9623 (1990).
274.
P. White and R. Breslow, "Molecular Mechanics Calculations on
Template-Directed Steroid Chlorinations: Are Transition States Rigidified by
the Geometric Trajectory Requirements for Effective Energy Transfer?" J.
Am. Chem. Soc. 112, 6842-6847 (1990).
273.
R. Breslow, "Enzyme Mimics", Pure & Appl. Chem., 62, 1859-1866
(1990).
272.
R. Breslow, J. W. Canary, M. Varney, S. T. Waddell, and D. Yang,
"Artificial Transaminases Linking Pyridoxamine to Binding Cavities:
Controlling the Geometry", J. Am. Chem. Soc. 112, 5212-5219 (1990).
271.
J. Light and R. Breslow, "A Water Soluble Tin Hydride Reagent"
Tetrahedron Lett. 31, 2957-2958 (1990).
270.
R. Breslow, D. Berger, and D.-L. Huang, "Bifunctional Zinc-Imidazole and
Zinc-Thiophenol Catalysts" J. Am. Chem. Soc. 112, 3686-3687 (1990).
269.
R. Breslow, "Partitioning Ratios and a Biochemical Kinetic Dilemma"
J. Chem. Ed. 67, 228-229 (1990).
268.
R. Breslow, "Enzyme Mimics" UCLA Symposia on Mol. and Cell. Biol.
110, 135-144 (1990).
267.
J. Light and R. Breslow, "The Hydrolysis of a Co(III) Chelated Amide
Catalyzed by an Internal Phosphonic Acid Group" Bioorg. Chem. 18, 63-77
(1990).
266.
R. Breslow and S. Chung, "Additional Flexibility Solves the Leaving Group
Problem in Cyclodextrin Acylation" Tetrahedron Lett. 31, 631-634 (1990).
265.
R. Breslow and T. Guo, "Surface Tension Measurements Show that Chaotropic
Salting-in Denaturants are not just Water-structure Breakers" Proc. Natl.
Acad. Sci. USA 87, 167-169 (1990).
1980-89
Top
264.
P. A. Marks, R. Breslow, and R. A. Rifkind, "Induced Cytodifferentiation
of Transformed Cells: an Approach to Cancer Treatment" Anticancer Drugs,
H. Tapiero, J. Robert, and T. J. Lampidis, eds., John Libbey Eurotext Ltd.
(1989).
263.
P. A. Marks, R. Breslow, and R. A. Rifkind, "Induced Cytodifferentiation
of Transformed Cells: an Approach to Cancer Treatment" J. Cellular
Pharmacol. 7-11 (1989).
262.
R. Breslow, "4n Pi Electron Triplet Species and their Potential Use in
Organic Ferromagnets" Mol. Cryst. Liq. Cryst. 176, 199-210 (1989).
261.
E. Anslyn and R. Breslow, "Proton Inventory of a Bifunctional Ribonuclease
Model" J. Am. Chem. Soc. 111, 8931-8932 (1989).
260.
R. Breslow, N. Greenspoon, T. Guo and R. Zarzycki, "Very Strong Binding of
Appropriate Substrates by Cyclodextrin Dimers" J. Am. Chem. Soc. 111,
8296-8297 (1989).
259.
R. Breslow and S. Chung, "A Novel Synthesis of Substituted Imidazoles, and
a Reexamination of a Purported Chymotrypsin Model" Tetrahedron Lett. 30,
4345-4346 (1989).
258.
P. A. Marks, R. Breslow, R. A. Rifkind, L. Ngo, and R. Singh,
"Polar/apolar Chemical Inducers of Differentiation of Transformed Cells:
Strategies to Improve Therapeutic Potential" Proc. Natl. Acad. Sci. USA,
86, 6358-6362 (1989).
257.
E. Anslyn and R. Breslow, "Geometric Evidence on the Ribonuclease Model
Mechanism", J. Am. Chem. Soc. 111, 5972-5973 (1989).
256.
R. Breslow, A. B. Brown, R. D. McCullough and P. W. White, "Substrate
Selectivity in Epoxidation by Metalloporphyrin and Metallosalen Catalysts
Carrying Binding Groups", J. Am. Chem. Soc. 111, 4517-4518 (1989).
255.
E. Anslyn and R. Breslow, "On the Mechanism of Catalysis by Ribonuclease:
Cleavage and Isomerization of the Dinucleotide UpU by Imidazole Buffers",
J. Am. Chem. Soc. 111, 4473-4482 (1989).
254.
R. Breslow, Deeng-Lih Huang, and E. Anslyn,"On the Mechanism of Action of
Ribonucleases: Dinucleotide Cleavage Catalyzed by Imidazole and Zn2+",
Proc. Natl. Acad. Sci. USA 86, 1746-1750 (1989).
253.
R. Batra and R. Breslow, "The Radical Relay Chlorination of Flexible
Nicotinate Esters", Heterocycles 28, 23-28 (1989).
252.
R. Batra and R. Breslow, "Double Functionalization of Cholestanol Directed
by Selective Bifunctional Templates", Tetrahedron Lett., 30, 535-538
(1989).
251.
H.-J. Thiem, M. Brandl and R. Breslow, "Molecular Modelling Calculations
on the Acylation of b-Cyclodextrin by Ferroceneacrylate Esters", J. Am.
Chem. Soc. 110, 8612-8616 (1988).
250.
R. Breslow and S. Singh, "Phosphate Ester Cleavage Catalyzed by
Bifunctional Zinc Complexes: Comments on the 'p-Nitrophenyl Ester
Syndrome'", Bioorg. Chem. 16, 408-417 (1988).
249.
R. Breslow, "Biomimetic Regioselective Template-directed
Functionalizations", Chemtracts Org. Chem. 1, 333-348 (1988).
248.
R. Breslow, J. Chmielewski, D. Foley, B. Johnson, N. Kumabe, M. Varney, and R.
Mehra, "Optically Active Amino Acid Synthesis by Artificial Transaminase
Enzymes", Tetrahedron, 44, 5515-5524 (1988).
247.
R. Breslow, "Artificial Enzymes: Studies Relevant to Reaction Mechanisms
of Enzymes and Enzymes Models", Proc. Robert A. Welch Found. Conf. on
Chem. Res., 31 73-89 (1988).
246.
R. Breslow and T. Guo, "Diels-Alder Reactions in Nonaqueous Polar
Solvents. Kinetic Effects of Chaotropic and Antichaotropic Agents and of
b-Cyclodextrin", J. Am. Chem. Soc., 110, 5613 (1988).
245.
R. Breslow, "Molecules that Mimic Enzymes", New Scientist, 119, 44
(1988).
244.
J. Thomaides, P. Maslak, and R. Breslow, "Electron-Rich Hexasubstituted
Benzene Derivatives and their Oxidized Cation Radicals, Dications with
Potential Triplet Ground States, and Polycations", J. Am. Chem. Soc., 110,
3970 (1988).
243.
R. Breslow and E. Kool, "A g-Cyclodextrin Thiazolium Salt Holoenzyme Mimic
for the Benzoin Condensation", Tetrahedron Lett., 29, 1635 (1988).
242.
E. T. Kool and R. Breslow, "Dichotomous Salt Effects in the Hydrophobic
Acceleration of the Benzoin Condensation", J. Am. Chem. Soc., 110, 1596
(1988).
241.
R. Breslow, "Selective Reactions Catalyzed by Enzyme Mimics", Chemica
Scripta, 27, 555 (1987).
240.
R. Breslow, "Artificial Enzymes", Cold Spring Harbor Symposia on
Quantitative Biology, 52, 75-81 (1987).
239.
R. Breslow, A. Adams, M. Brandl, T. Guo, and J. Hunger, "Heterocycles as
Templates in Directed Functionalization Reaction", Lectures in
Heterocyclic Chem., Vol. IX, 43 (1987).
238.
R. Breslow, M. Brandl, J. Hunger, N.J. Turro, K. Cassidy, K Krogh-Jespersen,
and J. D. Westbrook, "Pyridine Complexes of Chlorine Atoms", J. Am
Chem. Soc., 109, 7204-7026 (1987).
237.
T. J. Lepage and R. Breslow, "Charge-Transfer Complexes as Potential
Organic Ferromagnets", J. Am. Chem. Soc., 109, 6412-6421 (1987).
236.
R. Breslow and T. Guo, "The Thioxanthone System as a Template in Free
Radical Relay Chlorination of a Steroid", Tet. Letters, 28, 3187-3188
(1987).
235.
R. Breslow, M. Brandl, J. Hunger, and A.D. Adams, "Selective Steroid
Chlorinations Directed by Attached Pyridine Ester Templates", J. Am. Chem.
Soc., 109, 3799-3801 (1987).
234.
A. Schepartz and R. Breslow, "Hydrolysis of an Amide in a Carboxypeptidase
Model Using Co(III) and Bifunctional Catalysts", J. Am. Chem. Soc., 109,
1814-1826 (1987).
233.
J. Chmielewski and R. Breslow, "Increasing the Racemase Activity versus
Transaminase Activity of a Pyridoxal Enzyme Model by the Attachment of a Rigid
Base", Heterocycles, 25, 533 (1987).
232.
R. Breslow and A. Schepartz, "On the Mechanism of Peptide Cleavage by
Carboxypeptidase A and Related Enzymes", Chem. Letters, 1-4 (1987).
231.
R. Breslow, "Enzymes: The Machines of Life", Carolina Biological
Supply Co., Burlington, North Carolina (1986).
230.
A. Berkessel and R. Breslow, "On the Structures of Some Adducts of Biotin
with Electrophiles: Does Sulfur Transannular Interaction with the Carbonyl
Group Play a Role in the Chemistry or Biochemistry of Biotin?", Bioorganic
Chemistry, 14, 249-261 (1986).
229.
R. Breslow, "Biomimetic Control of Chemical Selectivity", Proceedings
of the XVIII Solvay Conference on Chemistry, Springer-Verlag, Berlin (1986).
228.
R. Breslow, "Directed Catalytic Functionalization Reactions" in
"New Synthetic Methodology and Functionally Interesting Compounds",
Kodansha Ltd., Tokyo Japan, 1986.
227.
U. Maitra and R. Breslow, "Conversion of the Cholesterol Sidechain to a
17-Acetyl Group by Remote Chlorination Reactions", Tet. Letters, 27, 3087
(1986).
226.
R. Breslow, "Approaches to Artificial Enzymes", Ann. N.Y Acad. Sci.,
471, 60 (1986).
225.
R. Breslow, ed.",International Symposium on Bioorganic Chemistry",
Ann. N.Y. Acad. Sci., 471 (1986).
224.
R. Breslow and M. Labelle, "Sequential General Base-Acid Catalysis in the
Hydrolysis of RNA by Imidazole", J. Am. Chem. Soc., 108, 2655-2659 (1986).
223.
S. Gellman, R. Petter and R. Breslow, "Catalytic Hydrolysis of a Phosphate
Triester by Tetracoordinated Zinc Complexes", J. Am. Chem. Soc., 108, 2388
(1986).
222.
R. Breslow, A.W. Czarnik, M. Lauer, R. Leppkes, J. Winkler, and S. Zimmerman,
"Mimics of Transaminase Enzymes", J. Am. Chem. Soc., l08, 1969-1978
(1986).
221.
R. Breslow, "Artificial Enzymes and Enzyme Models", Advances in
Enzymo logy and Related Areas of Molecular Biology, Alton Meister, Ed., John
Wiley & Sons, Inc., 58, 1-60 (1986).
220.
R. Breslow, "Attempts to Mimic Enzymes -- Report from the Battle
Front", Chemical Reactions in Organic and Inorganic Constrained Systems,
R. Setton, Eds., D. Reidel Publishing Company, l7-28 (1986).
219.
E. W. Svastits, J. H. Dawson, R. Breslow, and S. Gellman, "Functionalized
Nitrogen Atom Transfer Catalyzed by Cytochrome P-450", J. Am. Chem. Soc.,
107, 6427 (1985).
218.
T. LePage, K. Nakasuji, and R. Breslow, "Novel Conjugated Molecules from Oxydation
of a Cyclopentadienone Iron Tricarbonyl Complex", Tet. Letters, 26, 5919
(1985).
217.
I. Tabushi, Y. Kuroda, M. Yamada, H. Higashimura, and R. Breslow,
"A-(Modified B-6)-B[omega-amino(ethylamino)]-beta-cyclodextrin as an
Artificial B-6 Enzyme for Chiral Aminotransfer Reaction", J. Am. Chem.
Soc., 107, 5545 (1985).
216.
D. O'Krongly, S. R. Denmeade, M. Y. Chiang, and R. Breslow, "Efficient
Triple Coupling Reaction To Produce a Self-Adjusting Molecular Cage", J.
Am. Chem. Soc., 107, 5544 (1985).
215.
W. Weiner, J. Winkler, S. C. Zimmerman, A. W. Czarnik, and R. Breslow,
"Mimics of Tryptophan Synthetase and of Biochemical Dehydroalanine
Formation", J. Am. Chem. Soc., 107, 4093 (1985).
214.
R. Breslow, "Approaches to Organic Ferromagnets", Mol. Cryst. Liq.
Cryst. 125, 261 (1985).
213.
R. Corcoran, M. Labelle, A. W. Czarnik, and R. Breslow, "An Assay to
Determine the Kinetics of RNA Cleavage", Anal. Biochem. 144, 563-568
(1985).
212.
R. Breslow and U. Maitra, "Unusual Structural Effects on the Chemical
Degradation of Steroid Sidechains", Tet. Letters, 25, 5843 (1984).
211.
R. Breslow, P. Maslak, and J. Thomaides, "Synthesis of the
Hexaaminobenzene Derivative Hexaazaoctadecahydrocoronene (HOC) and Related
Cations", J. Am. Chem. Soc., 106, 6453 (1984).
210.
R. Breslow, "Enzyme Models Related to Inclusion Compounds" in
"Inclusion Compounds", J. L. Atwood and J. E. Davies, Eds., Academic
Press, Inc., Orlando, Fla., Vol. 3, 1984., pp. 473-501.
209.
D. Hilvert and R. Breslow, "Functionalized Cyclodextrins as Holoenzyme
Mimics of Thiamine-Dependent Enzymes", Bioorganic Chemistry, 12, 206
(1984).
208.
R. Breslow, F. Herman, and A. W. Schwabacher, "Loss of the Normal
Intramolecular Preferential Reactivity with a Highly Nonselective
Nitrene", J. Am. Chem. Soc., 106, 5359 (1984).
207.
Book Review. R. Breslow, "A Time to Remember. The Autobiography of a
Chemist", Alexander Todd, Science, 224, 1230 (1984).
206.
A.W. Czarnik and R. Breslow "Hexadeoxycycloheptaamylose-Pyridoxamine, An
Artificial Transaminase with a "Deeper" Binding Pocket",
Carbohydrate Research, 128, 133 (1984).
205.
R. Breslow, L.A. Deuring, "Concerning Phosphirenium Cations", Tet.
Letters, 25, 1345 (1984).
204.
R. Breslow, U. Maitra, "On the Origin of Product Selectivity in Aqueous
Diels-Alder Reactions", Tet. Letters, 25, 1239 (1984).
203.
R. Breslow, U. Maitra, and D. Heyer, "Remote Functionalization on the
Steroid beta-Face: Attack on an Angular Methyl Group, and Into the
Sidechain", Tet. Letters, 25, 1123 (1984).
202.
S.C. Zimmerman and R. Breslow, "Asymmetric Synthesis of Amino Acids by
Pyridoxamine Enzyme Analogues Utilizing General Base-Acid Catalysis", J.
Am. Chem. Soc., 106, 1490 (1984).
201.
J. Winkler, E. Coutouli-Argyropoulou, R. Leppkes, and R. Breslow,
"Artificial Transaminase Carrying a Synthetic Macrocyclic Binding
Group", J. Am. Chem. Soc., 105, 7198 (1983).
200.
R. Breslow and D. Heyer, "Directed Steroid Chlorination Catalyzed by an
Ion-Paired Template", Tet. Letters, 24, 5039 (1983).
199.
R. Breslow and J. Schwarz, "A Correlation of 13C NMR and Electrochemical
Data for Benzyllithium", J. Am. Chem. Soc., 105, 6795 (1983).
198.
R. Breslow and S.H. Gellman, "Intramolecular Nitrene C-H Insertions
Mediated by Transition-Metal Complexes as Nitrogen Analogues of Cytochrome P-450
Reactions", J. Am. Chem. Soc., 105, 6728-6729 (1983).
197.
R. Breslow, J. Hunt, R. Smiley, T. Tarnowski, " Synthesis of Polyimidazole
Ligands Related to Zinc Enzymes", J. Am. Chem. Soc., 105, 5337 (l983).
196.
R. Breslow, "Imitating the Selectivity of Enzymes", 2YC Distillate,
American Chemical Society, 1, 6 (1983).
195.
R. Breslow, J. Chin, D. Hilvert, G. Trainor, "Evidence for the General
Base Mechanism in Carboxypeptidase A-catalyzed Reactions. Partitioning Studies
on Nucleophiles and H218O Kinetic Isotope Effects." Proc. Nat. Acad. Sci.
USA, 80, 4585 (1983).
194.
R. Breslow, J. Chin, and D. Hilvert, "Studies on Zinc Enzymes and
Models", Inorg. Chim. Acta, 79, 61 (1983).
193.
W.J. le Noble, S. Srivastava, R. Breslow and G. Trainor, "Effect of Pressure
on Two Cyclodextrin-Promoted Ester Hydrolyses", J. Am. Chem. Soc., 105,
2745 (1983).
192.
R. Breslow, G. Trainor, and A. Ueno, "Optimization of Metallocene
Substrates for b-Cyclodextrin Reactions", J. Am. Chem. Soc., 105, 2739
(1983).
191.
R. Breslow, U. Maitra and D. Rideout, "Selective Diels-Alder Reactions in
Aqueous Solutions and Suspensions", Tet. Letters, 24, 1901 (1983).
190.
S.C. Zimmerman, A.W. Czarnik, and R. Breslow, "Intramolecular General
Base-Acid Catalysis in Transaminations Catalyzed by Pyridoxamine Enzyme
Analogues", J. Am. Chem. Soc., 105, 1694 (1983).
189.
R. Breslow, A.W. Czarnik, "Transaminations by Pyridoxamine Selectively
Attached at C-3 in beta-cyclodextrin", J. Am. Chem. Soc., 105, 1390
(1983).
188.
R. Breslow, "Approaches to Artificial Enzymes", in Biomimetic
Chemistry, Z.-I. Yoshida and N. Ise, eds., Kodansha Ltd. Publishing Co., Tokyo,
Japan, 1983, pp. 1-20.
187.
R. Breslow, contributing author to "Biochemistry", G. Zubay,
coordinating editor, Addison-Wesley Publishing Co., Reading, Massachusetts,
1983.
186.
R. Breslow, "Artificial Enzymes", Chemistry in Britain, 19, 126-131
(1983).
185.
R. Breslow, S.H. Gellman, "Tosylamidation of Cyclohexane by a Cytochrome
P-450 Model", J. Chem. Soc. Chem. Comm., 1400 (1982).
184.
R. Breslow, "Artificial Enzymes", Science, 218, 532-537 (1982).
183.
J. Chin, R. Breslow, "Some Reactions of Phenolic Maleamic Acids Relevant
to Carboxypeptidase Catalysis", Tet. Letters, 23, 4221 (1982).
182.
A. Ueno, R. Breslow, "Selective Sulfonation of a Secondary Hydroxyl Group
of Beta-cyclodextrin", Tet. Letters, 23, 3451(1982).
181.
R. Breslow, D. Heyer, "Catalytic Multiple Template-Directed Steroid
Chlorina tions", J. Am. Chem. Soc., 104, 2045 (1982).
180.
R. Breslow, "Stable 4n Pi Electron Triplet Molecules", Pure and
Applied Chemistry, 54, 927-938 (1982).
179.
R. Breslow, "Resolving Mechanistic Ambiguities", Frontiers of
Chemistry, IUPAC, K.J. Laidler, Ed., New York, 305-314 (1982).
178.
R. Breslow, B. Jaun, R.Q. Kluttz, C-Z Xia, "Ground State Pi-Electron
Triplet Molecules of Potential Use in the Synthesis of Organic
Ferromagnets", Tetrahedron, 38, 863 (1982).
177.
R. Breslow, D. Cortes, B. Jaun, R. Mitchell, "Studies on the Tricyanocyclo
propenyl System", Tet. Letters, 23, 795 (1982).
176.
R. Breslow, R. Rajagopalan, and J. Schwarz, "Selective Functionalization
of Doubly Coordinated Flexible Chains", J. Am. Chem. Soc., 103, 2905
(1981).
175.
G. Trainor, R. Breslow, "High Acylation Rates and Enantioselectivity with
Cyclodextrin Complexes of Rigid Substrates", J. Am. Chem. Soc., 103, 154
(1981).
174.
D. Rideout, R. Breslow, "Hydrophobic Acceleration of Diels-Alder
Reactions", J. Am. Chem. Soc., 102, 7816 (1980).
173.
R. Breslow, "Adjusting the Lock and Adjusting the Key in Cyclodextrin
Chemistry", in Biomimetic Chemistry" D. Dolphin, C. McKenna, Y.
Murakami and I. Tabushi, eds., Am. Chem. Soc., Washington, D.C.1980, p.1.
172.
B. Jaun, J. Schwarz, and R. Breslow, "Determination of the Basicities of
Benzyl, Allyl, and tert-Butylpropargyl Anions by Anodic Oxidation of
Organolithium Compounds", J. Am. Chem. Soc., 102, 5741 (1980).
171.
C. Wilcox and R. Breslow, "A Convenient Synthesis of bis-Dialkylamino
acetylenes", Tet. Letters, 21, 3241-3242 (1980).
170.
R. Breslow, "Biomimetic Control of Chemical Selectivity", Accts. of
Chem. Res., 13, 170 (1980).
169.
R. Breslow, P. Bovy, and C. Lipsey Hersh, "Reversing the Selectivity of
Cyclo dextrin Bisimidazole Ribonuclease Mimics by Changing the Catalyst
Geometry", J. Am. Chem. Soc., 102, 2115 (1980).
168.
R. Breslow and P.S. Pandey, "A Novel Synthesis of Aryl Orthoesters:
Trimethyl m-Iodoorthobenzoate", J. Org. Chem., 45, 740 (1980).
167.
R. Breslow, M.F. Czarniecki, J. Emert, and H. Hamaguchi, "Improved
Acylation Rates within Cyclodextrin Complexes from Flexible Capping of the
Cyclodextrin and from Adjustment of the Substrate Geometry", J. Am. Chem.
Soc., 102, 762 (1980).
166.
R. Breslow, M. Hammond, and M. Lauer, "Selective Transamination and Optical
Induction by a Beta-Cyclodextrin-Pyridoxamine Artificial Enzyme." J. Am.
Chem. Soc., 102, 421 (1980).
1970-79
Top
165.
R.C. Reuben, P.A. Marks, R.A. Rifkind, M. Terada, E. Fibach, U. Nudel, Y.
Gazitt and R. Breslow, "Induction of Erythroid Differentiation in Friend
Cells, Oncog. Viruses Host Cell Genes", [Proc. Oji Int. Semin. Genet.
Aspects Friend Virus Friend Cells], 5th, 303-317 (1979).
164.
R. Breslow, "Steroid Reactions Which Simulate the Selectivity of Enzymic Transformations",
Inf. Chim., 192-193, 129-134 (1979).
163.
R. Breslow, "Biomimetic Chemistry in Oriented Systems", Israel J.
Chem., 18, 187 (1979).
162.
R. Breslow, R.Q. Kluttz, and P. Khanna, "Oxidative Anodic Tosylamidation
at a Vanadium Electrode", Tet. Letters, 3273 (1979).
161.
R. Breslow, "Chemical Reactions of Steroids Which Imitate the Selectivity
of Enzymatic Transformations", J. Steroid Biochem., 11, 19 (1979).
160.
M.F. Czarniecki and R. Breslow, "Photochemical Probes for Model Membrane
Structures", J. Am. Chem. Soc., 101, 3675 (1979).
159.
R. Breslow, "Biomimetic Reactions in Steroids", Huaxue Tongbao, 6, 13
(1978).
158.
R. Breslow, S. Kitabatake, and J. Rothbard, "Photoreactions of Charged
Benzophenone with Amphiphiles in Micelles and Multicomponent Aggregates as
Conformational Probes", J. Am. Chem. Soc., 100, 8156 (1978).
157.
M.F. Czarniecki and R. Breslow, "Very Fast Acylation of Beta-Cyclodextrin
by Bound p-Nitrophenyl Ferrocinnamate", J. Am. Chem. Soc., 100, 7771
(1978).
156.
R. C. Reuben, P.L. Khanna, Y. Gazitt, R. Breslow, R.A. Rifkind, and P.A. Marks,
"Inducers of Erythroleukemic Differentiation; Relationship of Structure to
Activity Among Planar-Polar Compounds", J. Biol. Chem., 253, 4214-4218
(1978).
155.
C.C. Tang, D. Davalian, P. Huang, and R. Breslow, "Models for Metal
Binding Sites in Zinc Enzymes. Syntheses of Tris[4(5)-imidazoyl]
carbinol(4-TIC), Tris(2-imidazolyl)carbinol(2-TIC), and Related Ligands, and
Studies on Metal Complex Binding Constants and Spectra", J. Am. Chem.
Soc., 100, 3918 (1978).
154.
R. Breslow, J. Doherty, G. Guillot and C. Lipsey,
"Beta-Cyclodextrinyl-bisimidazole, a Model for Ribonuclease", J. Am.
Chem. Soc.,100, 3227-3229 (1978).
153.
R. Breslow and L.M. Maresca, "Template-Directed Epoxidation of Farnesol
and of Geranylgeraniol as Conformational Probes", Tet. Letters, 877
(1978).
152.
R. Breslow, J. Rothbard, F. Herman and M.L. Rodriguez, "Remote Functiona
lization Reactions as Conformational Probes for Flexible Alkyl Chains", J.
Am. Chem. Soc., 100, 1213 (1978).
151.
R. Breslow, "Studies on Enzyme Models and on the Enzyme Carboxypeptidase
A." Further Prospectives in Organic Chemistry, Ciba Foundation Symposium
53, Elsevier Publishing Company, Amsterdam (1978).
150.
R. Breslow, J. Pecoraro and T. Sugimoto, "Cyclopropenone", Org.
Synth., 57, 41 (1977).
149.
P.A. Marks, R. Reuben, E. Epner, R. Breslow, W. Cobb, A.E. Bogden and R.A.
Rifkind, "Induction of Murine Erythroleukemia Cells to Differentiate: A
Model for the Detection of New Anti-Tumor Drugs", Antibiot. Chemother,
(Basel) 23, 33 (1978).
148.
R. Breslow and J. Grant, "Electrochemical Determination of the Basicities
of Benzyl, Allyl, and Propargyl Anions, and a Study of Solvent and Electrolyte
Effects", J. Am. Chem. Soc., 99, 7745 (1977).
147.
R. Breslow and P.L. Khanna, "Further Evidence for the Formation of
Butalene in the Reaction of 1-Chloro-[2.2.0]Bicyclohexa-2,5-Dienes (Dewar
Chlorobenzenes) with a Strong Base", Tet. Letters, 3432 (1977).
146.
R. Breslow and D.L. Wernick, "Unified Picture of Mechanisms of Catalysis
by Carboxypeptidase A", Proc. Natl. Acad. Sci. USA, 74, 1303 (1977).
145.
B. Siegel, A. Pinter, and R. Breslow, "Synthesis of Cycloheptaamylose
2-,3-, and 6-Phosphoric Acids, and a Comparative Study of Their Effectiveness
as General Acid or General Base Catalysts with Bound Substrates", J. Am.
Chem. Soc., 99, 2309 (1977).
144.
R. Breslow, R.J. Corcoran, B.B. Snider, R.J. Doll, P.L. Khanna and R. Kaleya,
"Selective Halogenation of Steroids Using Attached Aryl Iodide
Templates", J. Am. Chem. Soc., 99, 905 (1977).
143.
R. Breslow and L.M. Maresca, "The Template-Directed Remote Epoxidation of
Olefins", Tet. Letters, 623 (1977).
142.
R.W. Johnson, T. Widlanski and R. Breslow, "Evidence for an Electron
Transfer Mechanism in the Coupling of Cyclopropenyl Cations with Cyclopropenyl
Anions", Tet. Letters, 4685 (1976).
141.
R. Breslow and R. Goodin, "An Electrochemical Determination of the pKa of
Isobutane", J. Am. Chem. Soc., 98, 6076 (1976).
140.
H.N.C. Wong, F. Sondheimer, R. Goodin and R. Breslow, "The Synthesis of
2,3,6,7-Dibenzobicyclo[6.2.0]deca-2,6,8-trien-4-yne-9,10-dione. The
Electrochemistry of Cyclobutenediones
("Cyclobutadienquinones")", Tet. Letters, 2715 (1976).
139.
R. Breslow and R. Goodin, "An Apparent Direct-Indirect Combined Mechanism
in Template-Directed Electrochemical Steroid Chlorination", Tet. Letters,
31, 2675 (1976).
138.
M.R. Wasielewski and R. Breslow, "Thermodynamic Measurements on
Unsubstituted Cyclopropenyl Radical and Anion, and Derivatives, by Second
Harmonic Alternating Current Voltammetry of Cyclopropenyl Cations", J. Am.
Chem. Soc., 98, 4222 (1976).
137.
R. Breslow, H. Kohn, and B. Siegel, "Methylated Cyclodextrin and a Cyclo
dextrin Polymer as Catalysts in Selective Anisole Chlorination", Tet.
Letters, 1645 (1976).
136.
R. Breslow, R.L. Wife, and D. Prezant, "Radical Relay Chlorination of
Cholestanol Directed by an Attached Diphenylsulfide Template", Tet.
Letters, 1925 (1976).
135.
R.C. Reuben, R.L. Wife, R. Breslow, R.A. Rifkind, and P.A. Marks, "A New
Group of Potent Inducers of Differentiation in Murine Erythroleukemia
Cells", Proc. Nat. Acad. Sci. USA, 73, 862-866(1976).
134.
R. Breslow and P.L. Khanna, "An Intramolecular Model for the Enzymatic
Insertion of Coenzyme B12 into Unactivated Carbon-Hydrogen Bonds", J. Am.
Chem. Soc., 98, 1297 (1976).
133.
R.L. Wife, D. Prezant, and R. Breslow, "Concerning the Regiospecificity
and Stereospecificity of Steroid Functionalization by Photolysis of an Attached
Benzophenone Ester", Tet. Letters, 517, (1976).
132.
R. Breslow and D. Wernick, "On the Mechanism of Catalysis by
Carboxypeptidase A", J. Am. Chem. Soc., 98, 259 (1976).
131.
R. Breslow and D.E. McClure, "Cooperative Catalysis of the Cleavage of an
Amide by Carboxylate and Phenolic Groups in a Carboxypeptidase Model", J.
Am. Chem. Soc., 98, 258 (1976).
130.
B. Siegel and R. Breslow, "Lyophobic Binding of Substrates by
Cyclodextrins in Nonaqueous Solvents", J. Am. Chem. Soc., 97, 6869 (1975).
129.
B.B. Snider, R.J. Corcoran, and R. Breslow, "Removal of the Steroid Side
Chain Using Remote Oxidation. Conversion of 3 Beta-Cholestanol to Androsterone
Acetate", J. Am. Chem. Soc., 97, 6580 (1975).
128.
R. Breslow, J. Napierski, and T.C. Clarke, "The Generation and Trapping of
Butalene", J. Am. Chem. Soc., 97, 6275 (1975).
127.
R. Breslow, R.W. Johnson, and A. Krebs, "Electrochemical Oxidation and
Reduction of a Tetraalkylated Cyclobutadiene", Tet. Letters, 40, 3443
(1975).
126.
M. Tanaka, J. Levy, M. Terada, R. Breslow, R.A. Rifkind, and P.A. Marks,
"Induction of Erythroid Differentiation in Murine Virus Infected
Erythroleukemia Cells by Highly Polar Compounds", Proc. Nat. Acad. Sci.
USA, 72, 1003-1007 (1975).
125.
J. Emert and R. Breslow, "Modification of the Cavity of Beta-Cyclodextrin
by Flexible Capping", J. Am. Chem. Soc., 97, 670 (1975).
124.
R. Breslow, D.E. McClure, R.S. Brown, and J. Eisenach, "Very Fast
Zinc-Catalyzed Hydrolysis of an Anhydride. A Model for the Rate and Mechanism
of Carboxypeptidase A Catalysis", J. Am. Chem. Soc., 97, 194 (1975).
123.
R. Breslow, "The Application of Electrochemistry to Some Physical Organic
Problems", Pure and Appl. Chem., 40, 493 (1974).
122.
R. Breslow, B.B. Snider, and R.J. Corcoran, "A Cortisone Synthesis Using
Remote Oxidation", J. Am. Chem. Soc., 96, 6792 (1974).
121.
R. Breslow, R.J. Corcoran, and B.B. Snider, "Remote Functionalization of
Steroids by a Radical Relay Mechanism", J. Am. Chem. Soc., 96, 6791
(1974).
120.
R. Breslow, A. Feiring, and F. Herman, "Intermolecular Insertion Reactions
of Phosphoryl Nitrenes", J. Am. Chem. Soc., 96, 5937 (1974).
119.
R. Breslow and T. Sugimoto, "Localized Transition States for Reactions of
Delocalized Molecules. Ionic and Radical Reductions of Chlorocyclopropenes with
Tri-n-butyltin Hydride", Tet. Letters, 28, 2437 (1974).
118.
R. Breslow and R.F. Drury, "Trapping of Electrochemically Generated Cyclo
pro penyl and Cycloheptatrienyl Anions by Charged Reagents", J. Am. Chem.
Soc., 96, 4702 (1974).
117.
R. Breslow, K. Ehrlich, T. Higgs, J. Pecoraro, and F. Zanker, "Some
Reactions of 1,2,3-Tribenzoylcyclopropene", Tet. Letters, 13, 1123 (1974).
116.
R. Breslow, R. Corcoran, J.A. Dale, S. Liu, and P. Kalicky, "Selective
Steroid Halogenations Directed by Proximity and Substituent Effects", J.
Am. Chem. Soc., 96, 1973 (1974).
115.
R. Breslow, M. Oda, and T. Sugimoto, "Bicyclotropones", J. Amer.
Chem. Soc., 96, 1639 (1974).
114.
R. Breslow, D. Murayama, R.F. Drury, and F. Sondheimer, "Electrochemistry of
Some Tetradehydro[18]annulenediones", J. Am. Chem. Soc., 96, 249 (1974).
113.
R. Breslow, "Cyclopentadienyl Cations", in Topics in Nonbenzenoid
Aromatic Chemistry, T. Nozoe, R. Breslow, K. Hafner, S. Ito, and I. Murata,
Eds., Vol. I, Hirokawa Publishing Co., Tokyo, 1973, p.81.
112.
T. Nozoe, R. Breslow, K. Hafner, S. Ito, and I. Murata, Eds., "Topics in
Nonbenzenoid Aromatic Chemistry", Vol. I, Hirokawa Publishing Co., Tokyo,
1973.
111.
R. Breslow, "Antiaromaticity", Accts. Chem. Res., 6, 393 (1973).
110.
R. Breslow, D. Murayama, S.-I. Murahashi, and R. Grubbs, "Quantitative
Assessment of the Antiaromaticity of Cyclobutadiene by Electro-chemical Studies
on Quinone Derivatives", J. Am. Chem. Soc., 95, 6688 (1973).
109.
M. Oda and R. Breslow, "A Facile l,5 Alkyl Shift Converting
Bicyclo[3.2.0]-hepta-1,3-diene into Spiro[2,4]hepta-4,6-diene", Tet.
Letters, 27, 2537 (1973).
108.
R. Breslow, J.M. Hoffman, Jr., and C. Perchonock, "Relative Reactivities
of the 5-Halocyclopentadienes in Diels-Alder and l,5 Shift Reactions",
Tet. Letters, 38, 3723 (1973).
107.
R. Breslow, S. Baldwin, T. Flechtner, P. Kalicky, S. Liu, and W. Washburn,
"Remote Oxidation of Steroids by Photolysis of Attached Benzophenone
Groups", J. Am. Chem. Soc., 95, 3251 (1973).
106.
P. Lechtken, R. Breslow, A.H. Schmidt, and N.J. Turro, "Thermal Rearrange
ment of Dewar Benzenes to Benzene Triplet States. Examples of Spin Forbidden
Nonadiabatic Pericyclic Reactions", J. Am. Chem. Soc., 95, 3025 (1973).
105.
M. Saunders, R. Berger, A. Jaffe, J.M. McBride, J. O'Neill, R. Breslow, J.M.
Hoffman, Jr., C. Perchonock, E. Wasserman, R.S. Hutton, and V.J. Kuck,
"Unsubstituted Cyclopentadienyl Cation, a Ground-State Triplet", J.
Am. Chem. Soc., 95, 3017 (1973).
104.
R.C. Benson, W.H. Flygare, M. Oda, and R. Breslow, "Microwave Spectrum,
Substitutional Structure, and Stark and Zeeman Effects in Cyclopropenone",
J. Am. Chem. Soc., 95, 2772 (1973).
103.
R. Breslow and Wm. Chu, "Thermodynamic Determination of pKa's of Weak
Hydrocarbon Acids Using Electrochemical Reduction Data. Triarylmethyl Anions,
Cycloheptatrienyl Anions, and Triphenyl- and Trialkylcyclopropenyl
Anions", J. Am. Chem. Soc., 95, 411 (1973).
102.
R. Breslow and S. Mazur, "Electrochemical Determination of pKR+ for Some
Antiaromatic Cyclopentadienyl Cations", J. Am. Chem. Soc., 95, 584 (1973).
101.
R. Breslow, "Biomimetic Chemistry", Centenary Lecture, Chem. Soc.
Rev., 1, 553 (1972).
100.
R. Breslow, M. Oda, and J. Pecoraro, "The Chemistry of Cyclopropenone.
Reactions at the Carbonyl Group, and l,2 Cleavages", Tet. Letters, 43,
4415 (1972).
99.
M. Oda, R. Breslow, and J. Pecoraro, "The Chemistry of Cyclopropenone.
Reactions at the Carbon-Carbon Double Bond", Tet. Letters, 43, 4419
(1972).
98.
R. Breslow, J. Napierski, and A. H. Schmidt, "Unsymmetrical Substituent
Effects on the Antiaromatic Transition for the Rearrangement of
Bicyclo-[2.2.0]hexadiene to Benzene", J. Am. Chem. Soc., 94, 5906 (1972).
97.
R. Breslow, "The Nature of Aromatic Molecules", Sci. Amer., 227, 32
(1972).
96.
R. Breslow and M. Oda, "The Isolation and Characterization of Pure
Cyclopropenone", J. Am. Chem. Soc., 94, 4787 (1972).
95.
R. Breslow, J.A. Dale, P. Kalicky, S.Y. Liu, and W.N. Washburn,
"Introduction of a 9(11) Double Bond into Steroids by Selective Free Radical
Halogenation", J. Am. Chem. Soc., 94, 3276 (1972).
94.
R. Breslow and J.M. Hoffman, Jr., "Solvolytic Cope Rearrangements",
J. Am. Chem. Soc., 94, 2111 (1972).
93.
R. Breslow and J.M. Hoffman, Jr., "Antiaromaticity in the Parent
Cyclopentadienyl Cation. Reaction of 5-Iodocyclopentadiene with Silver
Ion", J. Am. Chem. Soc., 94, 2110 (1972).
92.
R. Breslow, "Quantitative Studies on Aromaticity and
Antiaromaticity", Pure and Appl. Chem., 28, 111 (1971).
91.
R. Breslow and C. McAllister, "Intramolecular Bifunctional Catalysis of
Ester Hydrolysis by Metal Ion and Carboxylate in a Carboxypeptidase
Model", J. Am. Chem. Soc., 93, 7096 (1971).
90.
R. Breslow and M. Schmir, "Strongly Catalyzed Ligand-Ligand Reaction
Within a Mixed Metal Complex", J. Am. Chem. Soc., 93, 4960 (1971).
89.
R. Breslow and P. Campbell, "Selective Aromatic Substitution by
Hydrophobic Binding of a Substrate to a Simple Cyclodextrin Catalyst",
Bioorg. Chem., 1, 140 (1971).
88.
R. Breslow and P. Kalicky, "Remote Oxidation of Steroids by Reagents
Attached to Ring D. Introduction of a 9(11) Double Bond", J. Am. Chem.
Soc., 93, 3540 (1971).
87.
R. Breslow and P.C. Scholl, "Selective Oxidation of Unactivated Methylene
Groups by Reagent-Substrate Orientation in Mixed Complexes", J. Am. Chem.
Soc., 93, 2331 (1971).
86.
R. Breslow, "Studies on Enzyme Models", in Bioinorganic Chemistry,
Advances in Chemistry Series, No. 100, American Chemical Society, Washington,
1971.
85.
R. Breslow, H. Bozimo, and P. Wolf, "Bicyclo[l.l.0]butyl-2-carbinyl
Cations", Tet. Letters, 27, 2395 (1970).
84.
R. Breslow, R. Grubbs, and S.-I. Murahashi, "Electrochemical Evidence for
the Antiaromaticity of Cyclobutadiene", J. Am. Chem. Soc., 92, 4139
(1970).
83.
R. Breslow and W. Chu, "Electrochemical Determination of pKa's. Triphenyl
methanes and Cycloheptatriene", J. Am. Chem. Soc., 92, 2165 (1970).
82.
R. Breslow, R. Pagni, and W.N. Washburn, "Studies on a 7-Norbornenyl
Anion, A 'Bishomoantiaromatic' System", Tet. Letters, 8, 547 (1970).
81.
R. Breslow and L.E. Overman, "An 'Artificial Enzyme' Combining a Metal
Catalytic Group and a Hydrophobic Binding Cavity", J. Am. Chem. Soc., 92,
1075 (1970).
80.
R. Breslow, G. Ryan, and J.T. Groves, "Chlorocyclopropenes, Chloropropenyl
Cations, and Cyclopropenone", J. Am. Chem. Soc., 92, 988 (1970).
79.
R. Breslow and J.T. Groves, "Cyclopropenyl Cation. Synthesis and
Characterization", J. Am. Chem. Soc., 92, 984 (1970).
78.
R. Breslow and S.W. Baldwin, "Conversion of Cholestanol to 12-Ketocho lestanol
and to 14- and 8(14)-Cholestenol by Remote Oxidation", J. Am. Chem. Soc.,
92, 732 (1970).
77.
R. Breslow and W. Washburn, "Antiaromatic Destabilization of Cyclobuta
dieno cyclopentadienyl Anion", J. Am. Chem. Soc., 92, 427 (1970).
1960-69
Top
76.
R. Breslow, Organic Reaction Mechanisms, 2nd Ed., W.A. Benjamin, 1969.
75.
R. Breslow and K. Balasubramanian, "The pKa of Triphenylcyclopropene.
Electrochemical Determination of an Inaccessible Equilibrium Constant", J.
Am. Chem. Soc., 91, 5182 (1969).
74.
R. Breslow and P. Campbell, "Selective Aromatic Substitution within a
Cyclodextrin Mixed Complex", J. Am. Chem. Soc., 91, 3085 (1969).
73.
R. Breslow and M.A. Winnik, "Remote Oxidation of Unactivated Methylene
Groups", J. Am. Chem. Soc., 91, 3083 (1969).
72.
R. Breslow, Wm. Washburn, and R.G. Bergman, "Detection of Cyclobutadi eno
cyclopentadienyl Anion", J. Am. Chem. Soc., 91, 196 (1969).
71.
R. Breslow and I. Katz, "Relative Reactivities of p-Nitrophenyl Phosphate
and Phosphorothioate toward Alkaline Phosphatase and in Aqueous
Hydrolysis", J. Am. Chem. Soc., 90, 7376 (1968).
70.
L.D. Kispert, J.S. Hyde, Ch. DeBoer, D. LaFollette, and R. Breslow,
"Combined Endor and Electron Paramagnetic Resonance Techniques in a Study
of Some Low- Symmetry Triphenylmethyl Derivatives", J. Phys. Chem., 72,
4276 (1968).
69.
R. Breslow, "Kleine Antiaromatische Ringe", Angew. Chem., 80, 573
(1968); R. Breslow, "Small Antiaromatic Rings", Angew. Chem. Intl.
Ed., 7, 565 (1968).
68.
R. Breslow, L. Kaplan, and D. LaFollette, "Carbonium Ions with Multiple
Neighboring Groups. II. Physical Studies", J. Am. Chem. Soc., 90, 4056
(1968).
67.
R. Breslow, S. Garratt, L. Kaplan, and D. LaFollette, "Carbonium Ions with
Multiple Neighboring Groups. I. Synthesis", J. Am. Chem. Soc., 90, 4051
(1968).
66.
R. Breslow, "Antiaromatic Systems", Chem. in Britain, 4, 100 (1968).
65.
R. Breslow and M. Douek, "Antiaromatic Effects in Cyanocyclopropenyl
Anions", J. Am. Chem. Soc., 90, 2698 (1968).
64.
R. Breslow, S.S. Olin, and J.T. Groves, "Oxidative Cyclization of Farnesyl
Acetate by a Free Radical Path", Tet. Letters, 15, 1837 (1968).
63.
R. Grubbs, R. Breslow, R. Herber, and S.J. Lippard, "Studies of Iron
Tricarbonyl Cyclooctatetraenene Complexes", J. Am. Chem. Soc., 89, 6864
(1967).
62.
R. Breslow, J.T. Groves, and G. Ryan, "Cyclopropenyl Cation", J. Am.
Chem. Soc., 89, 5048 (1967).
61.
R. Breslow, J. Brown, and J.J. Gajewski, "Antiaromaticity of Cyclopropenyl
Anions", J. Am. Chem. Soc., 89, 4383 (1967).
60.
R. Breslow and G. Ryan, "Cyclopropenone", J. Am. Chem. Soc., 89, 3073
(1967).
59.
R. Breslow, R. Fairweather, and J. Keana, "Metal-Catalyzed Hydration of
Phenanthroline Nitrile", J. Am. Chem. Soc., 89, 2135 (1967).
58.
R. Breslow, H.W. Chang, R. Hill, and E. Wasserman, "Stable Triplet States
of Some Cyclopentadienyl Cations", J. Am. Chem. Soc., 89, 1112 (1967).
57.
Ch. DeBoer and R. Breslow, "The Photosensitized Dimerization of 1,2,3-
Triphenylcyclopropene", Tet. Letters, 11, 1033 (1967).
56.
R. Breslow, Organic Reaction Mechanisms, W.A. Benjamin, 1966.
55.
R. Breslow, J.T. Groves, and S.S. Olin, "A Novel Oxidative Terpene
Cyclization", Tet. Letters, 39, 4717 (1966).
54.
J.S. Hyde, R. Breslow, and Ch. DeBoer, "Observations of Conformational
Isomers by Electron Nuclear Double Resonance", J. Am. Chem. Soc., 88, 4763
(1966).
53.
R. Breslow, Wm. Horspool, H. Sugiyama, and Wm. Vitale "Octalene
Derivatives", J. Am. Chem. Soc., 88, 3677 (1965).
52.
R. Breslow and L.J. Altman, "Methylcyclopropenone and Related
Compounds", J. Am. Chem. Soc., 88, 504 (1966).
51.
R. Breslow, P. Gal, H.W. Chang, and L.J. Altman, "Isomerization of
Biscyclo propenyls to Benzenes", J. Am. Chem. Soc., 87, 5139 (1965).
50.
R. Breslow, D. Kivelevich, M.J. Mitchell, W. Fabian, and K. Wendel,
"Approaches to 'Push-Pull' Stabilized Cyclobutadienes", J. Am. Chem.
Soc., 87, 5132 (1965).
49.
R. Breslow and D. Chipman, "Mixed Metal Complexes as Enzyme Models. I.
Intracomplex Nucleophilic Catalysis by an Oxime Anion", J. Am. Chem. Soc.,
87, 4195 (1965).
48.
R. Breslow, "Aromatic Character", Chem. and Eng. News, 43, 90 (1965).
47.
R. Breslow and H.W. Chang, "Heptaphenylcycloheptatrienyl Anion", J.
Am. Chem. Soc., 87, 2200 (1965).
46.
R. Breslow, L.J. Altman, A. Krebs, E. Mohacsi, I. Murata, R.A. Peterson, and J.
Posner, "Substituted Cyclopropenones", J. Am. Chem. Soc., 87, 1326
(1965).
45.
R. Breslow, T. Eicher, A. Krebs, R.A. Peterson, and J. Posner,
"Diphenylcyclo propenone", J. Am. Chem. Soc., 87, 1320 (1965).
44.
R. Breslow, Wm. Vitale, and K. Wendel, "A Cyclooctatetraenocyclo penta
dienone", Tet. Letters, 6, 365 (1965).
43.
R. Breslow, R. Hill, and E. Wasserman, "Pentachlorocyclopentadienyl
Cation, A Ground-State Triplet", J. Am. Chem. Soc., 86, 5349 (1964).
42.
R. Breslow, "Concerning Carbanion Intermediates in Elimination
Reactions", Tet. Letters, 8, 399 (1964).
41.
R. Breslow and P. Dowd, "The Dimerization of Triphenylcyclopropene",
J. Am. Chem. Soc., 85, 2729 (1963).
40.
R. Breslow, H.W. Chang, Wm. A. Yager, "A Stable Triplet State of
Pentaphenyl-cyclopentadienyl Cation", J. Am. Chem. Soc., 85, 2033 (1963).
39.
R. Breslow, "Rearrangements in Small Ring Compounds", in Molecular
Rearrangements, P. de Mayo, Ed., Interscience Publishers, New York, 1963, pp.
233-294.
38.
R. Breslow and E. Mohacsi, "Studies on d-Orbital Conjugation. III.
Non-aromaticity of a Derivative of the l,3-Dithiepinyl Anion, a Ten pi-Electron
Conjugated System", J. Am. Chem. Soc., 85, 431 (1963).
37.
R. Breslow, J. Posner, and A. Krebs, "Synthesis of Cyclopropenones by a
Modified Favorskii Reaction", J. Am. Chem. Soc., 85, 234 (1963).
36.
R. Breslow, E. Barrett, and E. Mohacsi, "Free Radical Additions to
Squalene", Tet. Letters, 25, 1207 (1962).
35.
R. Breslow, H. Hover, and H.W. Chang, "The Synthesis and Stability of Some
Cyclopropenyl Cations with Alkyl Substituents", J. Am. Chem. Soc., 84,
3168 (1962).
34.
M.L. Bender and R. Breslow, "Mechanisms of Organic Reactions", in
Comprehensive Biochemistry, M. Florkin and E. Stotz, eds., vol.2, Elsevier, New
York, 1962.
33.
R. Breslow, J. Lockhart, and A. Small, "The Cyclopropenylcarbinyl Cation,
A Non-classical Carbonium Ion", J. Am. Chem. Soc., 84, 2793 (1962).
32.
R. Breslow, "The Mechanism of Thiamine Action: Predictions from Model
Experiments", Ann. N.Y. Acad. Sci., 98, 445, (1962).
31.
R. Breslow and H.W. Chang, "Heptaphenylcycloheptatrienyl Anion, A Singlet
with Potential Spin Degeneracy", J. Am. Chem. Soc., 84, 1484 (1962).
30.
R. Breslow and E. Mohacsi, "Studies on d-Orbital Conjugation. II. Lack of
Aromaticity in Systems Containing a Carbanion-Sulfone Double Bond", J. Am.
Chem. Soc., 84, 684 (1962).
29.
R. Breslow, "The Mechanism of Thiamine Action: Evidence from Studies on
Model Systems", CIBA Foundation Study Group II, J.A. Churchill Ltd., 1961,
p.65.
28.
R. Breslow, C. Yaroslavsky, and S. Yaroslavsky, "Structure of the
'Diaziridines' from Reaction of Azo-Dicarbonyl Compounds with Aliphatic Diazo
Compounds", Chem. And Ind., 1961 (1961).
27.
R. Breslow and E. Mohacsi, "Studies on d-Orbital Conjugation. I. The
Absence of a Through-Conjugation Effect in Some Sulfone Carbanions", J.
Am. Chem. Soc., 83, 4100 (1961).
26.
R. Breslow and H.W. Chang, "The Rearrangement of the
Pentaphenylcyclopentadienyl Cation", J. Am. Chem. Soc., 83, 3727 (1961).
25.
R. Breslow, J. Lockhart, and H.W. Chang, "The Diphenylcyclopropenyl
Cation. Synthesis and Stability", J. Am. Chem. Soc., 83, 2375 (1961).
24.
R. Breslow and H.W. Chang, "Triarylcyclopropenium Ions. Synthesis and
Stability in the Phenyl p-Anisyl Series", J. Am. Chem. Soc., 83, 2367
(1961).
23.
R. Breslow, Wm. Bahary, and Wm. Reinmuth, "Concerning the Stability of
Some Substituted Cyclopropenyl Radicals; Evidence from Polarography of the
Corresponding Cations", J. Am. Chem. Soc., 83,1763 (1961).
22.
R. Breslow and D. Kivelevich, "The Structure of Distyrinic Acid", J.
Org. Chem., 26, 679 (196l).
21.
R. Breslow, R. Boikess, and M. Battiste, "Some Cyclopropene
Rearrangements", Tet. Letters, 26, 42 (1960).
20.
R. Breslow and D. Chipman, "Concerning D'Yakonov's Cyclopropene
Synthesis", Chem. and Ind., 1105 (1960).
19.
R. Breslow and R. Peterson, "Dipropylcyclopropenone", J. Am. Chem.
Soc., 82, 4426 (1960).
18.
R. Breslow and M. Battiste, "An Unusual Rearrangement in the Cyclopropene
Series", J. Am. Chem. Soc., 82, 3626 (1960).
17.
R. Breslow and H. Hover, "The Synthesis of the Dipropylcyclopropenium
Ion", J. Am. Chem. Soc., 82, 2644 (1960).
16.
R. Breslow and E. McNelis, "On the Mechanism of Thiamine Action. VI.
2-Acetylthiazolium Salts as 'Active Acetate'", J. Am. Chem. Soc., 82, 2394
(1960).
15.
R. Breslow and L.N. Lukens, "On the Mechanism of Action of an Ascorbic
Acid-Dependent Nonenzymatic Hydroxylating System", J. Biol. Chem., 235,
292 (1960).
1953-59
Top
14.
R. Breslow, "On The Mechanism of the Formose Reaction", Tet. Letters,
21, 22 (1959).
13.
R. Breslow and P. Gal, "The Synthesis of Bistriphenylcyclopropenyl, an
Un-dissociated Dimer of the Triphenylcyclopropenyl Radical, and its Isomerization
to Hexaphenylbenzene", J. Am. Chem. Soc., 81, 4747 (1959).
12.
R. Breslow and E. McNelis, "Studies on Model Systems for Thiamine Action.
Synthesis of Reactive Intermediates, and Evidence on the Function of the
Pyrimidine Ring", J. Am. Chem. Soc., 81, 3080 (1959).
11.
R. Breslow, R. Haynie, and J. Mirra, "The Synthesis of
Diphenylcyclopropenone", J. Am. Chem. Soc., 81, 247 (1959).
10.
R. Breslow, R. Winter, and M. Battiste, "On Darling's Cyclopropene
Derivative and Its Rearrangement", J. Org. Chem., 24, 415 (1959).
9. R. Breslow and C. Yuan, "The sym-Triphenylcyclopropenyl
Cation, a Novel Aromatic System", J. Am. Chem. Soc., 80, 5991 (1958).
8.
R. Breslow and M. Battiste, "Detection of a Cyclopropenyl Anion by Deute
rium Exchange", Chem. and Ind., 1143 (1958).
7. R. Breslow, "On the Mechanism of Thiamine Action. IV.
Evidence from Studies on Model Systems", J. Am. Chem. Soc., 80, 3719
(1958).
6.
R. Breslow, "Synthesis of the s-Triphenylcyclopropenyl Cation", J.
Am. Chem. Soc., 79, 5318 (1957).
5.
R. Breslow, "Mechanism of Thiamine Action: Participation of a Thiazolium
Zwitterion, " Chem. and Ind., 893 (1957).
4.
R. Breslow, "Rapid Deuterium Exchange in Thiazolium Salts", J. Am.
Chem. Soc., 79, 1762 (1957).
3.
R. Breslow, "The Mechanism of Thiamine Action ", Chem. and Ind., BIF
Review, R. 28 (1956).
2.
G. Stork and R. Breslow, "The Rearrangement of Bromonorcedrenedicarboxylic
Acid", J. Am. Chem. Soc., 75, 3292 (1953).
1.
G. Stork and R. Breslow, "The Structure of Cedrene", J. Am. Chem. Soc.,
75, 3291 (1953).
S35.
R. Breslow, "Beyond the Molecular Frontier: Challenges for Chemistry and
Chemical Engineering," guest editorial, in Chemistry, American Chemical Society,
November/December 2003.
S34.
L. Fine and R. Breslow, "History of the Columbia Chemistry
Department," Columbia Today, in press.
S33.
R. Breslow, "Veal and Sausage Stew," in What's Cooking in Chemistry? How Leading
Chemists Succeed in the Kitchen, H. P. Bell, ed., Wiley-VCH, 2003.
S32.
R. Breslow, "Beyond the Molecular Frontier," Chemistry Business, October 2003, pp.
21-22.
S31.
R. Breslow, "Zinc," Chem. & Eng. News, September 8, 2003, p.86.
S30.
R. Breslow, "The Doctorate in Chemistry," Carnegie Essays on the Doctorate, 2003.
S29.
R. Breslow and M. Tirrell, CoChairs, Beyond the Molecular Frontier--Challenges for
Chemistry and Chemical Engineering, National Academies Press, 2003.
S28.
R. Breslow and A. Garritz, "Algunos retos de la quimica en el sigle
XXI," Educación
Química, 13, 222 (2002).
S27.
R. Breslow, Chemistry, in BIO2010: Undergraduate Education to Prepare Biomedical Research
Scientists, Lubert Stryer, chair, National Academies Press, 2002.
S26.
R. Breslow, "The Welcome Mat," C&E News Editorial, July 8, 2002.
S25.
R. Breslow and N. A. Le Bel, Organic Chemistry, in The American Chemical Society at 125: A
Recent History, 1976-2001, K. M. Reese, ed., American Chemical Society,
2002.
S24.
R. Breslow, Review of Stories of the Invisible, Philip Ball, Chemical & Engineering News, March
25, 2002, p. 48.
S23.
R. Breslow, "Not So General Chemistry," C&E News Editorial, July 30, 2001.
S22.
R. Breslow, speech in Green Chemistry and Engineering Conference Proceedings, 1997.
S21.
R. Breslow, forward to World Records in Chemistry, H.-J. Quadbeck-Seeger, Wiley-VCH, New
York, 1999.
S20.
R. Breslow, forward to Process Chemistry in the Pharmaceutical Industry, Kumar G.
Gadamasetti, Ed., Marcel Dekker Inc., NY, 1999.
S19.
R. Breslow, Chemistry
Today and Tomorrow, Japanese translation, Maruzen Co., Ltd., 1998.
S18.
R. Breslow, "Challenges for the Future of Chemistry,"in Chemical Research
and Beyond, P. Barkan, Ed., American Chemical Society, Washington D.C.
S17.
R. Breslow, "Education > Training" guest editorial Chem. and Eng.
News, March 16, 1998, p5.
S16.
R. Breslow, "ACS: A Responsive and Effective Organization," Chem. and Eng.
News, Dec. 8, 1997.
S15.
R. Breslow, "Chemistry in Science Museums," Chem. and Eng. News, February 17, 1997,
p. 50.
S14.
R. Breslow, "ACS and CMA: Partners in a Common Effort," CMA News,
December 1996, p.6.
S13.
R. Breslow, Chemistry: Today
and Tomorrow: The Central, Useful, and Creative Science, American Chemical
Society and Jones and Bartlett Publishers (1997).
S12.
R. Breslow, Message to New York/North Jersey ACS Members, The Indicator,
November, 1996, p. 15.
S11.
R. Breslow. "Personal Chemistry," Chemistry & Industry, September
16, 1996, p. 675.
S10.
R. Breslow, "The Greening of Chemistry," Chem and Eng. News, August
26, 1996, p. 72.
S9.
R. Breslow, "Some Challenges for Chemistry," Chem. and Eng. News,
July 8, 1996, p. 42.
S8.
R. Breslow, Guest Editorial, In Chemistry, 1996, vol.6, no. 3.
S7.
R. Breslow, "Don't surrender the science base," Chemistry &
Industry, 1996, p. 480.
S6.
R. Breslow, "Getting our Message Across," Chem and Eng. News, April
15, 1996, p. 35.
S5.
R. Breslow, "Basic Research and our Economic Future," Chem and Eng.
News, Feb. 12, 1996, p.79.
S4.
R. Breslow, "Interesting Times for Chemistry," Chem and Eng. News,
Jan. 1, 1996, p. 1.
S3.
R. Breslow, "The Education of Ph.D.s in Chemistry," Chem and Eng.
News, Dec. 11, 1995, p.65.
S2.
R. Breslow, "Layoffs of Chemical Professionals," Chem and Eng. News,
Feb. 6, 1995, p.29.
S1.
G. T. Seaborg, J. D. Baldeschwieler, J. Bigeleisen, R. Breslow, R. Geyer, J.
Ibers, T. Larson, Y. Lee, A. Schriesheim, R. Stein, R. Suttmeier, and J. Wei
"Chemistry and Chemical Engineering in the People's Republic of
China,"American Chemical Society, Washington, 1979.