Polymer Research
Center
FY 1995 $50,000
FY 1996 $10,700 |
|
Project Description and Goals: Strategic Initiative
Program funds were provided to support a team of chemists and chemical
engineers with research interests related to the properties of polymers
and polymer interfaces at the molecular level. Through collaborations involving
the cosponsoring of students and the sharing of resources, the goal is
for the team to pursue interdisciplinary research projects of interest
to the federal and state funding agencies, and industry. Most projects
undertaken by the Center provide junior faculty mentorship and serve to
better integrate research and graduate education.
Research projects are selected according to whether they
represent frontier polymer research, take advantage of existing technical
expertise at Columbia, and reinforce existing research teams and/or promote
new collaborations. The Center also engages in collaborations with other
local institutions including Polytechnic, SUNY
Stony Brook and UCONN at Storrs
in order to create bridges among local centers of strengths in the polymer/
interface field.
Status and Accomplishments
FY 1995: The Center’s research areas were selected
and teams were established involving senior and junior faculty. Selected
research areas included Polymer Thin Films and Coatings; Polymers at Interfaces;
Water Soluble Polymers; Polymerization Processes; and Undergraduate and
Graduate Education.
FY 1996: The main accomplishments of the Center
in FY 1996 included the following:
-
Faculty pairs involving one professor of Chemistry and one
professor of Chemical Engineering were teamed with students to pursue research
collaborations involving polymer topics. Topics were the adsorption of
polymers on surfaces, the mechanism of industrially important polymerizations,
and the development of novel spectroscopic tools to investigate polymers
at the interface.
-
Related to the Chemistry Department's computer-aided chemistry
education efforts, software tools were created with an emphasis on polymers.
These tools aided both educational and collaborative faculty-student research
projects. These efforts were implemented through linkages with the Engineering
School's Gateway Project.
-
Preparation for SEAS
Committee on Instruction (COI) revisions to undergraduate and graduate
courses in order to enhance the instruction in polymer science. In particular,
revisions to our introductory polymer course (AC4620) were submitted to
COI as were revisions to an existing graduate course dealing with the theory
of solutions and melts, to be renamed "Dynamics of Polymeric and Complex
Media" and to include topics relevant to biomedical engineering research.
The revised intro course was taught through CVN in the fall of 1996. This
course employed molecular simulation and animation in instruction, through
the Gateway Laboratory; this effort was showcased in Gateway’s dedication
as the Botwinick Lab.
-
Grant activities in FY 1996 included the submission of the
following proposals: National Science Foundation Engineering Division "Dynamic
and Non-equilibrium Aspects of Polymer Adsorption" for $125K per year for
3 years; National Science Foundation Chemistry Division "The Mechanism
of Free Radical Polymerization." for $125K per year for three years; New
York State Center for Advanced Technology Initiative, with SUNY at Stony
Brook "Studies of Polymer-Based Liquid Quartz Alignment Layers" for $125K;
and New York State Center for Advanced Technology Initiative, with Polytechnic
Institute of New York "Development of Sensors Based on Quartz Crystal Microbalances"
for $20K.
FY 1997: The main accomplishments of the Center in
FY 1997 included the following:
-
Several new research teams were formed during FY 1997 within
the Center.
-
A workshop has been held for training in the use of molecular
simulations software in the Gateway Lab. About 20 Columbia University staff
from chemistry and SEAS were trained along with industrial participants
from the New York City area. The software is in use for instruction in
the freshman chemistry and the introduction to polymers course and is planned
for use in advanced undergraduate courses in biophysics and materials science
during 1997.
-
A workshop was held in fall of 1997 to develop a focal theme
for research efforts around "dendrimer" polymers (highly branched polymers
with tremendous technological potential). Leaders in the new field were
invited to CU for talks and discussions. Several new teams and proposals
are expected to result.
-
An outreach effort to the Los
Alamos National Lab (LANL) was to promote the use of neutron scattering
and neutron reflectometry for polymer research at Columbia. Professor Durning
spent half of his sabbatical at the LANL neutron scattering center (Jan.
- Aug. ’97), formed a team to design a new neutron reflectometer at LANL
and to develop a scientific research effort exploiting the new spectrometer.
The team includes five co-principal investigators from other academic institutions
and national labs.
-
An outreach effort was launched to the University of Connecticut
at Storrs which has a leading polymer science program to promote a student
exchange and research collaboration program.
-
Fundraising activities for FY 1997 included securing the
following grants submitted in FY 1996: NSF Engineering Division "Dynamic
and Non-equilibrium Aspects of Polymer Adsorption" for $335,000; NSF Chemistry
Division "The Mechanism of Free Radical Polymerization" for $275,000; and
NSF's IUCRC Program a planning grant of $10,000 toward a proposal dealing
with novel properties of surfactant adsorption on interfaces. The grant
to the New York State Center for Advanced Technology Initiative, with Polytechnic
Institute of New York "Development of Sensors Based on Quartz Crystal Microbalances"
for $20K and a grant to the NSF's Major Research Instrumentation Program
"High Resolution Optical Microscopy for Synthetic and Biological Materials
Research" $870K total were denied. Current pending proposals include: New
York State Center for Advanced Technology Initiative, with SUNY at Stony
Brook "Studies of Polymer-Based Liquid Quartz Alignment Layers" for $125K;
DOE BES Division "Surface and Interface Neutron Spectrometer at Los Alamos
Neutron Scattering Center $3.6M; and NSF Engineering Division "Synergistic
Interactions Between Additives During Copper Electrodeposition" for $125,000
per year for 3 years.
Project Leaders: Nicholas
Turro, Professor, Chemistry; and Christopher
Durning, Associate Professor, Chemical Engineering