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Draft.1 Leonard Fine<Macintosh HD:Temporary Items:AutoRecovery save of C1404.003. Leonard Fine<Macintosh HD:Temporary Items:AutoRecovery save of C1404.003. Leonard Fine<Macintosh HD:Temporary Items:AutoRecovery save of C1404.003. Leonard Fine/Macintosh HD:Temporary Items:Word Work File A 2 Leonard FineHZip 100.C1404.2002 Stuff:C1404.2002.Exam 1:C1404.003.Exam1.2002. Draft.1 QSA]5 hho(.^`o()^`o() $ $ ^$ `o(@ @ ^@ `.^`.L^`L.^`.^`.PLP^P`L.^`o()^`.pLp^p`L.@ @ ^@ `.^`.L^`L.^`.^`.PLP^P`L.A]QS@ TNX''"#P%P@PP8@PP@@P*PX@GTimes New Roman5Symbol3 Arial3Times5 Geneva"1hb&b&aA!0%L"=1chem Leonard Finey MelendezChemistry Dept.SC NUKEChemistry DeptLynna G Avila BrontDr. Elena Bront de AvilaSheppard Computer Labs Joan RaitanoB. VenkataramanChemistry Department Jeff KinderKaren RawlingsL. 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Fine Alison BiusoDepartment of Chemistry ChemistryTauqir Mabel YeeRoweena Bacchus ANNE WATTERS!!!!!!!!!"""""""""""""""!!!!!!!!!              !!!"""####$$$%%%%%%%%&&&&&&%%%%%$$$$###"""!!   3444455555556666666666666666666666666666666666655555555555555554444444444444444444444444444444444444444444444455444444444433333322222111111111111111222334445567788999::;;;<<<<==<<<<<<<<;;;;::::99988877777777777777777888999::;;;<<<===>>>>>>>?????????????????????????????????????????????????????????????????@@@@@@@@@@@@@@@@???????????????????????????????????????????????????????????????????????????????????>>>>>>>>>>>>>>>>==================================>>>>>>>>>>>>>>>=======<<<<<<<<<<<<<;;;;;;;::::::98877655432110/.-,,+*))(''&%%$$$$###############"""""""""""""""""""""####$$$%%%&&&&'''(((())))))*********))))((('''&&&&%%%%%%$$$%%%%%%%&&&&''''((()))****++++++++,,,,,,,++++++*****)))))((((((((((((((((((()))****+++,,,---...///0000000000000000///////////////////....................--------------------------------..---------,,,,,,,,,+++++++++++++,,,,---...///0001122233444556677888888888888888888888888888888889999999999999999999999999999999999988888888888888887777OGPRAcademic assistant-BBBBBBBBBBBBBBCCBA@?>=<:97642 1 / - + ) ' % # !  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BolmUniversit degli StudiInstitut fr Organische ChemieAK Hey-HawkinskurzWaro NAKANISHI Gellman GroupAndrew J. GellmanJulie L. d'ItriALDO VECCHIETTI Mark Buelowvirginia cornish Jenny CosshamJohn Wiley & Sons Ltd Ron SiclariPlowmanaltoftJOhn Wiley & Sons Ltd. Janie Curtis PRENTICE HALLWord DevelopmentRichard BaggaleyJohn Wiley & Sons Ltd. John Wiley Martin SharpbottomleFrances M Seeney Toni ChowLynne CialdellaSydney StewartDanielle Jones Terry ColeJohn Wiley & Sons GRIFFINLESLEYANGELA POULTERAngela Poulter Phil Bishopsampford Joel Kalish David SidmanGregory St John Verity WaiteWiley Jennifer WoodeamesDirect phone number: (01243) 770209Direct fax number: (01243) 77042Fax Cov Sheet To:Peter HeilbrunnFax5144From:Jim DicksDate:6th March 1997bject:CARPages:1Please contact Sarah Kiely on (01243) 770402 if you have any difficulties reiving this fax As promised, here's a list of cars rolling over in the next three or four months. et me know if any are of interest or if you need more details. An early response would be helpful as ere are others we may offer these cars to after you. CarAge in FY98 MileageCitroen ZX4 yrs +7000 +Audi 804 yrs +75,000 +Mazda 3234 yrs 100,000 +Golf GTi4 yrs +63,000 +BMW 520 i6 Gregory St. Johns 24 Priory Crescent Southsea Hants PO4 8RL Dear Caryn John Wiley & Sons Ltd Retirement Benefits Scheme I enclo your Statement of Benefits on Leing Service for your information. This shows the pension benefits payable to you on retirement and to youspouse on your death. The Guaranteed Minimum Pension ("GMP") referred to is roughly equivalent to the State Additiol Pension you would have earned had you not been contracted-out of the State Earnings-Related Pension Scheme Joseph van VlijmenMeAuthorized CustomerAnn-Marie HalliganDERADRAGreg Mark RoseIan JackMaureen Murphy Sarah Kiely Adrian WestonwilliamssilkAVSWalter Sneader Marie Cribbinholloway Gwenda Keates Laura ConleySamantha SpeightsgriffinGRIFFINAcademic Computing ServicePlanet InternetOnbekend minie msa MicrosoftSYSTEM ID3 6565 Edward Barrow John HealyGateway 2000 Licensed UserAnna Chisholm McIntosh Anna Jellinek ANNA JELLINEK Andrew Braidcrosse PATRICK KELLYticknerMichael R. OsuchpagetEE deptEE dept. Tim Sullivan Steve Lenz Robert MeyersJohn Wiley & So9 " e b j;' Doris Chen Doris W Chen S.T. CeyerOITJennifer & Michael Thomas Office of Information Technology Jacob SydneyLesley College David J. SaabplatinumUser Support x8770 Laury & Wayne Joe Johnson Kathy HolmesJillian MillerElijahKaejae & Jurawalesley college Karol LynchMicrosoft Office UserWaldreidHC Karen TraveloMike RobertsonGay Su Pinnell Polly TrueCaitlin Florschutz Jan RossiComputer ServicesComputer Services.BellcoreEd Longo Bob CondursoTera Lungstrom Bill CalhounRonald B. SobelAlexis DobbinsInformation Technology Cary Toor Ramez GhattasCharles P. Kapp Thang Nguyen Alan Kramer Diane JonesRonnie RasslerMarcia F. Kessler ReferenceStever Robbins Ellen HermanHarvard Business School Jan MartinezIPS Associates, Inc. Stuart SpiresAuthorized Gateway Customer IT Specialist Mark PelofskyJonathan D. Callaghan Kirsten BeitzElaine Backman'The Wellness Community - Greater BostonJeanette LurieNancy Peck-GreyEXEDIT Operations Group Judy StahlTeresa M. AmabileHoward Stevenson Roberta BrownHarvard Tim BernsteinSonja Broomfield-SmithLeslie A. Jeng P.J. Boxer SEI Corp.David E. 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Ewing Scott Harmon David KanallyCSS, SMG John Moore Mandy Lee David Upton CLC NY-HUBJohn C. BurrisAuthorized User Susan Brumfield & Deirdre MeehanSusan BrumfieldResearch & Technology Lab Bret Baird. Bobbie Harder Faye RaleyClayton HansellStuart Whiting Sharon Burks Jeffrey Cohen Jeff Willis Angela Averymaryalic Mary-Alice TRIO Apsetup M.A. LeRoyColleen Teahan Jeff Raikes Sharon Decker Daniel CondeSergio A. Pineda Pamela MeansMichael A. Feinberg Greg GoffDerek W. Whittle Lisa Morganchrisen Kathy Collins Rita MichellLars Johansson Jim WilsonBev AuldBruce N. Petersen Gayle Andrews susan cole margaret cobbTawni ChristensenSteve TrautmanLewisl Ed McCahillCraig A. FiebigChristy Keolker Carl StorkJeff M. Johnson amy acherEHQtimthBob LunnDavid J. ParkerJeffrey A. BennettShari G. SmithMargaret Adams Bob Forgrave Richard TaitK. Quinn Ellis Brad Chase Rick Segal Wink ThorneTRIO Diana Ryesky Mike J. FloraColeen Cantwell Karen AustLaura M. TorinaJames E. Torina Eric Straub Dave Meltzer Yusuf MehdiBrian Emanuels Bob Taniguchi Betsy Tinney Bill Snyder Martin LeahyDebbie Johnson Jeff Drexlermarye Randy Radke John Wood Mike Houston Kevin Dolan Mark BarryBarbara L. Lovelace Gail Cerra Ralph Huskey Angie Rice Steven HenryllSymuserErik ChristoffersenSusan M. Emery Oliver Ryan Kate Wilson Edge GroupADSSIDFrederica L. BaldwinPeter F. GastaldiJose Luis BallesterosSarayu Srinivasan Ranjay GulatiMartin GARGIULOFrancis Andrew Tapon Andrew McAfee Jack Oswaldash%Lawson Mardon Thermaplate Corporation Nick DowdMarion Greenhalgh Alison HilyerBoulogneLMTLAWSON MARDON LABELStmAnne PrfontaineLAWSON MARDON LABEL MONTREAL Joan Farrell Hicks BobSherill AllardMike YoskovitzLAWSON MARDON PACKAGING INC. Thomas Brudlo lawson mardonYoskovitz MikeLawon Mardon Packaging Inc. Bob HicksRonald G. JamiesonPeter SchorlingLAURA VALENCIAxxxxxxxxxxxxxxxxxxxxxLMSINGEN LM SINGENMicrosoft CorporationTechnical Architecture Lepomme RudiWuestenhagen Barbararamos sue/heatherLAWSON MARDONLAWSON MARDON LABELLawson Mardon PackagingLawson Mardon Label Tom SumidawagnernamerbCenter for Effective Org Bruce LandonJulian Wimbush Jeff HirisGil Preuss and Terri BrownCristine BanfieldGabrielle LajoieJohn R. LofgrenDenise RossmanNMS USERBrian Emanuels Laura CordovanoW. McDonald BucknanuTest Libandrea schulman Pat JohnsonResearch AssociateMicroAge A. Goode User Bruce NappiTherese TrimburStefania CalabiStefania NappiAnthony A. Atkinson robin cooperhbsKSG Computer Lab Pentium #3Massachusetts Technology ParkMASS TECH PARK Pentium #2Katharine Daley FennellyIng.Mauri Renato FORMAZIONEStefano MainettiPOLITECNICO DI MILANOProfessor Nava Pliskin Karen Wilson MBA Program Michael YangOPIM, The Wharton SchoolRichard D. TaborsRichard J. Roth, Jr.Steve Goldberg Tolga ErgunayRichard J. Roth,Sr.Jason A. Hicks Karen LewisStephen J. MorganRobert W. KleinChristine FairchildJames WaldroopSheila Lirio Marcelo Anna C. SheenAlan D. McKirbyAnita Williams WoolleyRutledgeKim and Matt BloomCBADaniel M. Cable Kim B. ClarkJames K. Sebenius Women IncCarliss BaldwinDanny Struebing Adam Tratt Manish Vij Sam HobsonMichael Milkowits Andy PeastonRamsauer ChristianMaureen Walkerrip Report  TIME \@ "MMMM d, yyyy" September 29, 1997 Company: Swiss Life (Rentenanstalt) Postfach, CH-802Zurich, Switzerland Soodmattenstrasse 4; CH-8134 Adiswil, Switzerland By: William D. ea, Director of Corporate Relations, Executive Education Date of Visit: September 17, 1997 Contac Dr. Edoud Marmier, Director IS tel: 41-1-711-3773 fax: 41-1-711-5007 e-mail: edouard.marmier@swissli.ch Dr. Roland Engel, Manager IS tel: 41-711-4171 fax: 41-1-711-5183 e-mail: rold.engel@swisslife.ch Dr. Jean Weydert, Vice Director, IS tel: 41-1-711-5084 fax: 41-1-711-4nitedDominion97HarvardLMacintosh HD:Applications:Microsoft Office:Microsoft Word 6:UnitedDominion97HarvardLMantosh HD:Applications:Microsoft Office:Microsoft Word 6:UnitedDominion97HarvardPMacintosh HD:Applications:Microft Office:Microsoft Word 6:Templates:TripReportHarvardPMacintosh HD:Applications:Microsoft Office:Microsoft Wo 6:Templates:TripReportHarvardPMintosh HD:Applications:Microsoft Office:Microsoft Word 6:Templates:TripReportHarvardPMacintosh HD:Applicaons:Microsoft Office:Microsoft Word 6:Templates:TripReportHarvardPMacintosh HD:Applications:Microsoft Office:Miosoft Word 6:Templates:TripReportHarvard1Macintosh HD:Desktop Folder:Trips 9/97:TripReportHarvardUntitled:Swi Trip ReportDonald and Judith BockErica R. Deighton KnowledgeNet$Knowledge Gosia Wozny Martine Haas P Bennett Laurie Gamble Ann MarguliesUIS David Flash Anne KleinHarvard UniversityPatrick Sileo Sarah PanettaRobert E. GuntherSTEELE Tom EisenmannILC Jane GillMGH-USER Paul Kennedy IT Manager Scott Andrews Eric Mankin Carl Bruke Ed TuttleJohn Dan FosterRichard StarfieldEmployee Nancy Confrey Kevin Huh Jonathan KatzDennis A. Williams Devang Patel Russell ChangCynthia Houston Saul AltabetAnalysis Group, Inc. Bruce StangleSSOA John S. ZukHinzBarbara FeinbergMAD Lisa SchorrEmily Kistler LawsonRobert LillenessJohn E. ZdanowskiSean M. and Julie C. Daltonmichael beckwithEDWARD U. MILLER Jeffrey Flaum Igal Litovsky Derek Brown David Teten Peter Munson Unknown Warren Blanchard ROBERT BLACKDan BellRuss Vanderpool CONOR RYANKaren Hopper WruckMark J Cotteleer Hau L. LeeKimberly Phillips Lauren OkumDouglas R. RogersTodd E. Graves Cindy OlnickChrister SjholmMaryfrances Fabbril&R atrick SileoSteeleAnne Prfontaine haron Deckerr"!"!"! "! 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Yoshino Pat Johnson ayle Andrews ngie RiceNelis Jill Enos Susie HwangMarcelo MoralesDomingo Alejandro MoreiraJulie SteinbergNathan HamiltonMalcolm SalterRowland S. Blake Jeff LazarusChisholmZAPPAROLI RaffaellaCEDlorena galettiRoberta Micheli0Formaper - Azienda Speciale C.C.I.A.A. di Milano Monica PeregoC.E.D.Giulio Bosis FabioOscar F.J.F. WeissCranfield School of Management Joe PeppardGiulio ZotteriMacintosh UserRobert L. Ruffin Jr. Tom Van VleckJames P. O'Connor Steve Crocker Alden HartAndrew Jackson CyberCashCyber Lou FelderDenise ParedesFES steve klebeLG 2d Revision aliasLarry 2d Revision aliasLarry 2d Revision AliasLarry 2d revision alias Larry GilbertPatti McCaffreyMAC 280cLG2Melisa EstradaWilliam Melton ConferenceLaura Selvakumar R.Robbie TischerBob LindenbergLocus Computing Corporation P V Surendran d.v.prasadD S RAOBruce Patterson James LumLevi B. StamperWalt StoneburnerPhilip Pointer Steve Ball Gray Matter Lois R. 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Draft.1  QSA]5 hho(.hho(.^`o()^`o() $ $ ^$ `o(@ @ ^@ `.^`.L^`L.^`.^`.PLP^P`L.^`o()^`.pLp^p`L.@ @ ^@ `.^`.L^`L.^`.^`.PLP^P`L.A]QS@a TN & F?h & F C$>*)*+14=JLNXYZ[]^_`lnopq|~ ""#"$"+","-"0@1f1f0f1f1g1 g18@1 g1Z@1g1l@0,g10g1Dg1Fg1Hg1Jg1p@0Ng0Pg1Rg1jg0ng0pg1rg1tg1g0g0g1g1g0g0g1g1g0g0g1g1g1g0g0g1g1 h0h0h1h1*h0.h00h12h1Jh0Nh0Ph1Rh1jh0nh0ph1rh1h0r@0t@1h0@0h0@1h0\@0:@0@@008@00@@0*0X@0*[@0Z@1h0[@0([@0*[@GTimes New Roman5Symbol3 Arial3Times5 Geneva"qhb&b&aA!>0%=1chem Leonard Fine 0902-247D-11D6-A8F9-000502F7D29D} Oh+'0X    ,8@HP'1sschemofhemNormalf Leonard FineWo3onMicrosoft Word 8.0d@0@`ո@zָa FMicrosoft Word DocumentNB6WWord.Document.8 ՜.+,D՜.+,0 hp  'chemitlA%b 1 Title 6> _PID_GUID'AN{E4ACnts) (XX Points) (XX Points) (XX Points) TOTAL above.2 h*h.h2hJhNhRhjhnhrhhhhhhh0JmH5;CJ 5>*CJ5CJRhphrhhhhdh 1$ t   & F1$ t  s -jbjb nkk"]666666~D 8L BBXXXXXX,L6XXXXX866XXX888X6X6XJ6666X88r h66DhC HtPrinted Last Name: |___|___|___|___|___|___|___|___|___|___|___|___| Printed First Name: |___|___|___|___|___|___|___|___|___|___|___|___| Social Security # |___|___|___| |___|___| |___|___|___| School: |___|Barnard |___|College |___|Engineering |___|General Studies Chemistry 1404y Exam 1 February 18, 2002 Instructions Fill in your name and CUID number as indicated above. On the bubble sheet: 1) On Side 2 of the Bubble Sheet print your first and last name in the box provided. 2) Then fill in the Identification No. in the space provided and as indicated. Your Identification No. is your Social Security Number. 3) Using a soft lead pencil, blacken the one response that best answers the question or completes the statement. There is only one correct answer to each question. Any question with more than one answer will not be counted. Your score will be the total number of correct answers; therefore, it is to your advantage to answer every question. 4) There are 27 questions. They are equally weighted. Under no circumstances are you to make any other marks... anywhere on the bubble sheet... except in the appropriate bubbles for marking an answer you believe to be correct. You may write on the exam sheets themselves for the purpose of doing calculations.... but do not write on the bubble sheet. A periodic table of the elements can be found on page10 of this exam. A SCRATCH SHEET is provided on PAGE 11. Check the front blackboard for time remaining, last-minute corrections and additional information. You will have 75 minutes to complete the exam. When you have finished the exam or at the end of the allowed time, deposit your exam questions and bubble sheets in the separate boxes provided at the front of the room. Do not forget! Print your first and last names in the box provided (1) on the bubble sheet, and (2) on the front page of the 11 pages of this exam. Remember! It is your responsibility to ensure that your bubble sheet and exam sheets are properly identified. 1. Consider the following molecules: H2C=CH2 ethene (ethylene) HC=CH ethyne (acetylene) CH3HC=CH2 propene (propylene) CH3C=CH propyne (methyl acetylene) Account for the fact that ethane and ethyne exhibit no C-to-C multiple bond infrared stretching frequencies (bands) in the infrared whereas propene and propyne do ANS: Ethene and ethyne (unlike propene and propyne) have no CC-to-C multiple bond stretching frequencies because they are symmetrical and do not undergo a change in dipole moment when excited. 2. Consider the symmetric stretching modes of the following molecules: carbon dioxide CO2 (OCO) dinitrogen oxide N2O (NNO) ozone O3 cyanogen NCCN Identify which are infrared active and explain why the others are not. ANS: Carbon dioxide and cyanogen, being linear and symmetrical molecules, would not result in a change in dipole moment and are therefore inactive. If ozone were linear and not bent it would be inactive but it is bent and is active. 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BishopStephen BellerNSStephen E. Beller, Ph.D.sebBINNEY & COMPANYIBM ConsultPing Group KEN BINNEY Office User Martin MatskoMartin J MatskoNCQA Gary StraussKenneth W. BinneyValued Gateway 2000 CustomerPreferred CustomerS"S 5bS UtS& ]IBM ConSFESFEKaren KawaguchiVince"National Health Data Systems, Inc.Norman D. Stein, Ph.D.Stephen E. BellerAST Preferred CustomerAlistair Young Wally Hauck . Wally HauckS b5S tUS &]ROSANNE D'AUSILIOKathryn H. ClarkeDavid FriedmanfcMerrill Corporationjour Barry Honig John KupiecjfeldmanLABO CHIMIE BIOMOLECULAIREDENERDr. Karen du PlooyProf. Dr. H.-D. ScharfAK Prof. Dr. C. BolmUniversit degli StudiInstitut fr Organische ChemieAK Hey-HawkinskurzWaro NAKANISHI Gellman GroupAndrew J. GellmanJulie L. d'ItriALDO VECCHIETTI Mark Buelowvirginia cornish Jenny CosshamJohn Wiley & Sons Ltd Ron SiclariPlowmanaltoftJOhn Wiley & Sons Ltd. Janie Curtis PRENTICE HALLWord DevelopmentRichard BaggaleyJohn Wiley & Sons Ltd. John Wiley Martin SharpbottomleFrances M Seeney Toni ChowLynne CialdellaSydney StewartDanielle Jones Terry ColeJohn Wiley & Sons GRIFFINLESLEYANGELA POULTERAngela Poulter Phil Bishopsampford Joel Kalish David SidmanGregory St John Verity WaiteWiley Jennifer WoodeamesDirect phone number: (01243) 770209Direct fax number: (01243) 77042Fax Cov Sheet To:Peter HeilbrunnFax5144From:Jim DicksDate:6th March 1997bject:CARPages:1Please contact Sarah Kiely on (01243) 770402 if you have any difficulties reiving this fax As promised, here's a list of cars rolling over in the next three or four months. et me know if any are of interest or if you need more details. An early response would be helpful as ere are others we may offer these cars to after you. CarAge in FY98 MileageCitroen ZX4 yrs +7000 +Audi 804 yrs +75,000 +Mazda 3234 yrs 100,000 +Golf GTi4 yrs +63,000 +BMW 520 i6 Gregory St. Johns 24 Priory Crescent Southsea Hants PO4 8RL Dear Caryn John Wiley & Sons Ltd Retirement Benefits Scheme I enclo your Statement of Benefits on Leing Service for your information. This shows the pension benefits payable to you on retirement and to youspouse on your death. The Guaranteed Minimum Pension ("GMP") referred to is roughly equivalent to the State Additiol Pension you would have earned had you not been contracted-out of the State Earnings-Related Pension Scheme Joseph van VlijmenMeAuthorized CustomerAnn-Marie HalliganDERADRAGreg Mark RoseIan JackMaureen Murphy Sarah Kiely Adrian WestonwilliamssilkAVSWalter Sneader Marie Cribbinholloway Gwenda Keates Laura ConleySamantha SpeightsgriffinGRIFFINAcademic Computing ServicePlanet InternetOnbekend minie msa MicrosoftSYSTEM ID3 6565 Edward Barrow John HealyGateway 2000 Licensed UserAnna Chisholm McIntosh Anna Jellinek ANNA JELLINEK Andrew Braidcrosse PATRICK KELLYticknerMichael R. OsuchpagetEE deptEE dept. Tim Sullivan Steve Lenz Robert MeyersJohn Wiley & So9 " e b j;' Doris Chen Doris W Chen S.T. CeyerOITJennifer & Michael Thomas Office of Information Technology Jacob SydneyLesley College David J. SaabplatinumUser Support x8770 Laury & Wayne Joe Johnson Kathy HolmesJillian MillerElijahKaejae & Jurawalesley college Karol LynchMicrosoft Office UserWaldreidHC Karen TraveloMike RobertsonGay Su Pinnell Polly TrueCaitlin Florschutz Jan RossiComputer ServicesComputer Services.BellcoreEd Longo Bob CondursoTera Lungstrom Bill CalhounRonald B. SobelAlexis DobbinsInformation Technology Cary Toor Ramez GhattasCharles P. Kapp Thang Nguyen Alan Kramer Diane JonesRonnie RasslerMarcia F. Kessler ReferenceStever Robbins Ellen HermanHarvard Business School Jan MartinezIPS Associates, Inc. Stuart SpiresAuthorized Gateway Customer IT Specialist Mark PelofskyJonathan D. Callaghan Kirsten BeitzElaine Backman'The Wellness Community - Greater BostonJeanette LurieNancy Peck-GreyEXEDIT Operations Group Judy StahlTeresa M. AmabileHoward Stevenson Roberta BrownHarvard Tim BernsteinSonja Broomfield-SmithLeslie A. Jeng P.J. Boxer SEI Corp.David E. 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Sebenius Women IncCarliss BaldwinDanny Struebing Adam Tratt Manish Vij Sam HobsonMichael Milkowits Andy PeastonRamsauer ChristianMaureen Walkerrip Report  TIME \@ "MMMM d, yyyy" September 29, 1997 Company: Swiss Life (Rentenanstalt) Postfach, CH-802Zurich, Switzerland Soodmattenstrasse 4; CH-8134 Adiswil, Switzerland By: William D. ea, Director of Corporate Relations, Executive Education Date of Visit: September 17, 1997 Contac Dr. Edoud Marmier, Director IS tel: 41-1-711-3773 fax: 41-1-711-5007 e-mail: edouard.marmier@swissli.ch Dr. Roland Engel, Manager IS tel: 41-711-4171 fax: 41-1-711-5183 e-mail: rold.engel@swisslife.ch Dr. Jean Weydert, Vice Director, IS tel: 41-1-711-5084 fax: 41-1-711-4nitedDominion97HarvardLMacintosh HD:Applications:Microsoft Office:Microsoft Word 6:UnitedDominion97HarvardLMantosh HD:Applications:Microsoft Office:Microsoft Word 6:UnitedDominion97HarvardPMacintosh HD:Applications:Microft Office:Microsoft Word 6:Templates:TripReportHarvardPMacintosh HD:Applications:Microsoft Office:Microsoft Wo 6:Templates:TripReportHarvardPMintosh HD:Applications:Microsoft Office:Microsoft Word 6:Templates:TripReportHarvardPMacintosh HD:Applicaons:Microsoft Office:Microsoft Word 6:Templates:TripReportHarvardPMacintosh HD:Applications:Microsoft Office:Miosoft Word 6:Templates:TripReportHarvard1Macintosh HD:Desktop Folder:Trips 9/97:TripReportHarvardUntitled:Swi Trip ReportDonald and Judith BockErica R. 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Vanden Plas CPU # 08073 Jon North Dan MichaelVincent Trujillo Susan Kleinlen fine!-3GMfm-49@KQV\elqxs}} D K   OR ,0| OVNPpr !!!!!!!!!!!!-"/"T"n"OZBQ~Z`s} , - $ %Hypr " Q S T"n"chem:Wolfeman HD:Desktop Folder:C1404.Draft.Exam 1.2002.SpectrachemsWolfeman HD:Desktop Folder:TEACHING.Current:C1404 CURRENT.1/22/02:C1404.2002.Exam 1:C1404.Draft.Exam 1.2002.SpectrachemsWolfeman HD:Desktop Folder:TEACHING.Current:C1404 CURRENT.1/22/02:C1404.2002.Exam 1:C1404.Draft.Exam 1.2002.Spectra Leonard Fine9Macintosh HD:Desktop Folder:C1404.003.Exam1.2002. Draft.1 Leonard Fine<Macintosh HD:Temporary Items:AutoRecovery save of C1404.003. Leonard Fine<Macintosh HD:Temporary Items:AutoRecovery save of C1404.003. Leonard Fine<Macintosh HD:Temporary Items:AutoRecovery save of C1404.003. Leonard Fine/Macintosh HD:Temporary Items:Word Work File A 2 Leonard FineHZip 100.C1404.2002 Stuff:C1404.2002.Exam 1:C1404.003.Exam1.2002. Draft.1  QSA]5 hho(.hho(.^`o()^`o() $ $ ^$ `o(@ @ ^@ `.^`.L^`L.^`.^`.PLP^P`L.^`o()^`.pLp^p`L.@ @ ^@ `.^`.L^`L.^`.^`.PLP^P`L.A]QS@ a   TN & F?h & F C$>*C$Eƀb' & F & FC$ FL)*+14=JLNXYZ[]^_`lnopq|~1 hnru78<}^M=s "$&'(QR*+lq{]^b# !R"S"T"c"d"k"l"m"0@1f1f0f1f1g1 g18@1 g1Z@1g1l@0,g10g1Dg1Fg1Hg1Jg1p@0Ng0Pg1Rg1jg0ng0pg1rg1tg1g0g0g1g1g0g0g1g1g0g0g1g1g1g0g0g1g1 h0h0h1h1*h0.h00h12h1Jh0Nh0Ph1Rh1jh0nh0ph1rh1h0r@0t@1h0@0h0@1h0\@0:@0@@0n0V@0 @0n0|-@00"n0.n16n0rY@1x10"# =1chem Leonard Fine FMicrosoft Word DocumentNB6WWord.Document.8 ՜.+,D՜.+,0 hp  'chemitl<"b 1 Title 6> _PID_GUID'AN{E4AC0902-247D-11D6-A8F9-000502F7D29D} Oh+'0X    ,8@HP'1sschemofhemNormalf Leonard FineWo4onMicrosoft Word 8.0d@ԭ@`ո@׸ N 9. 10. 19. 9 (n*n,n.n0n2n4n6nFnHnJnLnNnPnRnTnVnXnZn\n^n`nbndnfnhnjnlnnnpnpnrntnvnxnzn|n~nnnnnnnnnnnnnnnnnnndhs $-jbjb tkkT"]6666668 \, ff||||||,L@Ld6|||||P66|||PPP|6|6|Jhh6666|PP*r$h66hD HPrinted Last Name: |___|___|___|___|___|___|___|___|___|___|___|___| Printed First Name: |___|___|___|___|___|___|___|___|___|___|___|___| Social Security # |___|___|___| |___|___| |___|___|___| School: |___|Barnard |___|College |___|Engineering |___|General Studies Chemistry 1404y Exam 1 February 18, 2002 Instructions Fill in your name and CUID number as indicated above. On the bubble sheet: 1) On Side 2 of the Bubble Sheet print your first and last name in the box provided. 2) Then fill in the Identification No. in the space provided and as indicated. Your Identification No. is your Social Security Number. 3) Using a soft lead pencil, blacken the one response that best answers the question or completes the statement. There is only one correct answer to each question. Any question with more than one answer will not be counted. Your score will be the total number of correct answers; therefore, it is to your advantage to answer every question. 4) There are 27 questions. They are equally weighted. Under no circumstances are you to make any other marks... anywhere on the bubble sheet... except in the appropriate bubbles for marking an answer you believe to be correct. You may write on the exam sheets themselves for the purpose of doing calculations.... but do not write on the bubble sheet. A periodic table of the elements can be found on page10 of this exam. A SCRATCH SHEET is provided on PAGE 11. Check the front blackboard for time remaining, last-minute corrections and additional information. You will have 75 minutes to complete the exam. When you have finished the exam or at the end of the allowed time, deposit your exam questions and bubble sheets in the separate boxes provided at the front of the room. Do not forget! Print your first and last names in the box provided (1) on the bubble sheet, and (2) on the front page of the 11 pages of this exam. Remember! It is your responsibility to ensure that your bubble sheet and exam sheets are properly identified. 1. Consider the following molecules: H2C=CH2 ethene (ethylene) HC=CH ethyne (acetylene) CH3HC=CH2 propene (propylene) CH3C=CH propyne (methyl acetylene) Account for the fact that ethane and ethyne exhibit no C-to-C multiple bond infrared stretching frequencies (bands) in the infrared whereas propene and propyne do ANS: Ethene and ethyne (unlike propene and propyne) have no CC-to-C multiple bond stretching frequencies because they are symmetrical and do not undergo a change in dipole moment when excited. 2. Consider the symmetric stretching modes of the following molecules: carbon dioxide CO2 (OCO) dinitrogen oxide N2O (NNO) ozone O3 cyanogen NCCN Identify which are infrared active and explain why the others are not. ANS: Carbon dioxide and cyanogen, being linear and symmetrical molecules, would not result in a change in dipole moment and are therefore inactive. If ozone were linear and not bent it would be inactive but it is bent and is active. 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