Enthalpy, Spontaneous Change, Reversibility, Disorder, Entropy, and the Second Law of Thermodynamics; Gibbs Free Energy; DS and DG; Trouton's Rule; Chemical Reactions and DG; DG, and the Equilibrium Constant; Effect of Temperature on DG and the Equilibrium Constant.
Examples and Exercises: 11-1 through 11-10.
Problems: 9, 11, 17, 25, 27, 33, 39, 49, 53, 59, 63, 73, 87, 95, and the Cumulative Problem.
Suggested Completion Date: April 6
Sections 12-1 (Metals and Metallurgy) and 12-2 (Balancing Redox Equations) need to be studied on your own. Not much class time will be devoted to these secions as special topics but the redox chemistry and the half-reaction method for balancing equations will be needed throughout the rest of this (as well as the next) chapter. If you have trouble with the method, your recitation instructor will provide help. The sections on electrochemical cells and Faraday's Laws constitute the bulk of the issues to be described here. Read the section on electrometallurgy and consider the redox reactions described.
Examples and Exercises: 12-1 through 12-6.
Problems: 11, 17, 25, 27, 33, 35, 37, 39, 45, 59, 63, 73, 77, and the Cumulative Problem.
Suggested Completion Date: April 13
Free energy, cell voltage and half-cell potentials; the Nernst equation; equilibrium constants and cell potentials; batteries and fuel cells; corrosion and its prevention.
Examples and Exercises: 13-1 through 13-9.
Problems: 3, 5, 7, 9, 11, 13, 19, 25, 29, 37, 45, and the Cumulative Problem.
Suggested Completion Date: April 20
Rates of chemical reactions, the concentration and time dependency of the rate of a chemical reaction, and the order of a chemical reaction. Mechanisms of chemical reactions. Temperature dependency of the reaction rate. Catalytic processses.
Examples and Exercises: 14-1 through 14-9.
Problems: 7, 9, 15, 19, 21, 25, 29, 33, 37, 47, 53, 65, and the Cumulative Problem.
Suggested Completion Date: April 27