S3444Q - ORGANIC CHEMISTRY II - SU 2001 (7/2-8/9, Fri 7/6)

 

Professor Irving J. Borowitz gborowit@cybernex.net

 

Columbia University, Box 3122 Havemeyer Hall, 212-854-2056  - Lectures 10:45-12:20 M-R

Lecture Room -320 Havemeyer            Office 343 Hav-                  Office Hours –M-R 12:30-1:00 PM

Recitation – 9:00-10:30 AM      Room 320 Hav, Recitator:                   ; Office Hours: 12:30-1:30 PM,

@chem.columbia.edu 212-854-     Revised

TEXT:  T. W. G. Solomons, C. Fryle "Organic Chemistry," 7th Edition, J. Wiley, New York, 2000; T. W. G. Solomons, C. Fryle, R. Johnson "Study Guide to Organic Chemistry," 7th Edition, J. Wiley, 2000.  This book contains answers to all homework problems, extra problems, and self-tests.

MODELS:  A set of Molecular Models, S. Darling, is highly recommended and is available for purchase in the bookstore. The Chemistry Department Office of Undergraduate Instruction is 318 H.

COMPUTER SOFTWARE: T. W. G. Solomons, "Organic Chemistry," CD-ROM, “Chem TV”, and other Organic Topics, Mechanisms, and Spectroscopy software is available in 343 H.

 

COURSE OUTLINE SECOND SUMMER SESSION 2001

Dates              wk            Chap.             Description                                                                                                   

M   7/02           1      15  Electrophilic Aromatic Substitution (review; was covered in S 3443 lectures)

T    7/03      1    2.16*      UV (Ch. 13.9 brief), start IR (Ch. 2.16)

W  7/04           1         Independence Day Celebration

R    7/05           1      2.16*.      Spectroscopic Methods of Structure Determination: IR (*also p. 648, 753, 818, 1039)

F    7/06      1    9.1-.11 Nuclear Magnetic Resonance Spectroscopy. Note extra class.

 

M   7/09      2    9      NMR Spectroscopy, continued. 13C-NMR, Interpreting H-NMR Spectra, Problems.

T    7/10           2      9, 16          NMR Spectroscopy (finish); start Ch. 16 Aldehydes and Ketones I.

W  7/11      2      2.16*, 9,15      EXAM 1 (10:00 AM- 12:30 PM

R    7/12           2      16      Aldehydes and Ketones I, continued. Additions to the C=O, Oxidation.

 

M   7/16      3    16, 17 Finish Ch. 16, start Ch. 17 Aldehydes and Ketones II. Aldol Reactions.

T    7/17      3    17      Aldehydes and Ketones II cont’d  Reactions at the a-Carbon.

W  7/18      3    17      continued. Lithium Enolates, Silyl Enol Ethers; start Ch. 18.

R    7/19           3      18  Carboxylic Acids and Their Deriv. Acidity, Preparation, Nucleophilic Acyl Subst.

 

M   7/23      4    18, B      continued. Nucleophilic Subst at Acyl Carbon, Step-Growth Polymers; start Ch. 19.

T    7/24           4      19  Synthesis and Reactions of b-Dicarbonyls: More Chem of Enolate Ions, Enamines.

W  7/25           4     16-18, B    EXAM 2 (10:00 AM - 12:30 PM)

R    7/26           4      20  Amines.

F   7/27                                         Last Drop Date

 

M   7/30           5      21  Phenols and Aryl Halides: Nucleophilic Aromatic Subst.- Addn-Elim and Benzyne.

T    7/31           5      19,20,21      EXAM 3 (10:00 AM - 12:30 PM)

W  8/01           5      22      Carbohydrates.     

R    8/02           5      22  continued.

 

M   8/06           6      23, D      Lipids; Thiol Esters and Lipid Biosynthesis (p 928-941; p. 354 )

T    8/07           6      24 Amino Acids and Proteins.

W  8/08           6      24  continued, Review for final exam.

R   8/09           6      Comprehensive - 22,23,D,24      FINAL EXAM      (10 AM - 1 PM)      

GRADING POLICY:  [(Best 2 of 3 Exams)+(Final Exam)]/3 = Final Average

NOTES:  There are NO make-up exams. A missed exam counts as the dropped exam. It is strongly recommended that all exams be taken. Speak to us if you need a tutor. Computer assisted learning is available at 343 Havemeyer.