Molina and Rowland,
Nature 1974
In the stratosphere…
CFCs :
CCl
2
F
2
CClF
2
•
+
Cl•
Cl•
+
O
3
ClO•
+
O
2
ClO• +
O
Cl•
+
O
2
Net:
O
+
O
3
2O
2
The Cl acts basically as a catalyst:
~10,000 O
3
will break down to O
2
for every Cl
•