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Chapter 18: Enols and Enolates

18.1 The a Carbon Atom and Its Hydrogens
18.2 a Halogenation of Aldehydes and Ketones
18.3 Mechanism of a Halogenation of Aldehydes and Ketones
18.4 Enolization and Enol Content
18.5 Stabilized Enols
18.6 Base-Catalyzed Enolization. Enolate Anions
18.7 The Haloform Reaction

18.8 Some Chemical and Stereochemical Consequences of Enolization

18.9 The Aldol Condensation: Aldehydes
18.10 The Aldol Condensation: Ketones
18.11 Mixed Aldol Condensations
18.12 The Aldol Condensation in Synthetic Organic Chemistry

18.13 Effects of Conjugation in a, b-Unsaturated Aldehydes and Ketones
18.14 Conjugate Nucleophilic Addition to a, b-Unsaturated Carbonyl Compounds
18.15 Additions of Carbanions to a, b-Unsaturated Ketones: The Michael Reaction
18.16 Conjugate Addition of Organocopper Reagents to a, b-Unsaturated Carbonyl Compounds
18.17 Alkylation of Enolate Anions
18.18 Summary


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