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Chapter 22: Amines

22.1 Amine Nomenclature
22.2 Structure and Bonding
22.3 Physical Properties

22.4 Measures of Amine Basicity
22.5 Basicity of Amines
22.6 Tetraalkylammonium Salts as Phase-Transfer Catalysts

22.7 Reactions That Lead to Amines: A Review and a Preview
22.8 Preparation of Amines by Alkylation of Ammonia
22.9 The Gabriel Synthesis of Primary Alkylamines
22.10 Preparation of Amines by Reduction
22.11 Reductive Amination
22.12 Reactions of Amines: A Review and a Preview
22.13 Reactions of Amines with Alkyl Halides
22.14 The Hofmann Elimination

22.15 Electrophilic Aromatic Substitution in Arylamines
22.16 Nitrosation of Alkylamines
22.17 Nitrosation of Arylamines
22.18 Synthetic Transformations of Aryl Diazonium Salts
22.19 Azo Coupling
22.20 Spectroscopic Analysis of Amines
22.21 Mass Spectrometry of Amines
22.22 Summary



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