Jack Norton
Department of Chemistry

work : +1 212-854-7644
jrn11@columbia.edu


Norton Group

Publications


"Synthesis and Structural Characterization of Cp2- and (CpMe)2-ligated Titanaaziridines and Titanaoxiranes with Fast Enantiomer Interconversion Rates", Ling Li, Kathleen E. Kristian, Arthur Han, Jack R. Norton,* and Wesley Sattler, in press, Organometallics.

“On the Reaction of Arylacetic Acids with Isonitriles”, J. G. Polisar and J. R. Norton*, in press, Tetrahedron.

153.     “Hydrogen Atom Transfer from (η5-C5H5)Cr(CO)3H to Alkynes: Applications to Radical Cyclizations”, D. P. Estes, W. Sattler, and J. R. Norton*, J. Am. Chem. Soc. 2012, 134, 15512–15518. DOI: 10.1021/ja306120n

152.     “Cobaloxime-Mediated Radical Cyclization under H2; Evidence for Formation of a Co-H Bond and Kinetics of H• Transfer”, Gang Li, Mary E. Pulling, Deven P. Estes and Jack R. Norton*, J. Am. Chem. Soc. 2012, 134, 14662–14665. DOI: 10.1021/ja306037w

151.     “Synthesis, Electrochemistry, and Reactivity of New Iridium (III) and Rhodium (III) Hydrides”, Yue Hu, Ling Li, Anthoy P. Shaw, Jack R. Norton*, Wesley Sattler and Yi Rong, Organometallics 2012, 31, 5058–5064. DOI: 10.1021/om300398r

150.     “Thermodynamics of the metal-hydrogen bonds in (η5-C55)M(CO)2H (M = Fe, Ru, Os)”, D. P. Estes, A. K. Vannucci, A. R. Hall, D. L. Lichtenberger,* J. R. Norton*, Organometallics, 2011, 30, 3444-3447.

149.     “Facile Reaction of Carboxylic Acids with Isonitriles in Toluene”, J. G. Polisar, L. Li, J. R. Norton*, Tetrahedron Letters, 2011, 52, 2933-2934.

148.     “Zirconium-Catalyzed Carboalumination of α-Olefins and Chain Growth of Aluminum Alkyls:  Kinetics and Mechanism”, J. M. Camara, R. A. Petros, J. R. Norton*, J. Am. Chem. Soc., 2011, 133, 5263-5273.

147.  “Catalysis Involving the H• Transfer Reactions of First-Row Transition Metals”, J. Hartung, D. M. Smith, and J. R. Norton*, in Catalysis without Precious Metals; Bullock, M., Ed., Wiley-VCH: Weinheim, in preparation.

146.  “Synthesis, Electrochemistry, and Reactivity of Half-Sandwich Ruthenium Complexes Bearing Metallocene-Based Bisphosphines”, A. P. Shaw, J. R. Norton,* D. Buccella, L. A. Sites, S. S. Kleinbach, D. A. Jarem, K. M. Bocage, and C. Nataro*, Organometallics, 2009, in press.

145.  “Mechanism of Insertion of Alkynes into a “Constrained Geometry” Zirconaaziridine:  Dissociation of PMe3 is Faster than from the Corresponding Cp2 Complex”, K. E. Kristian, M. Iimura, S. A. Cummings, J. R. Norton*, K. E. Janak, and K. Pang, Organometallics, 2009, 28, 493-498.

144.  “Using a Two-Step Hydride Transfer to Achieve 1,4 Reduction in the Catalytic Hydrogenation of an Acyl Pyridinium Cation”, A. P. Shaw, B. L. Ryland, M. J. Franklin, J. R. Norton,* J. Y.-C. Chen and M. L. Hall, J. Org. Chem. 2008, 73, 9668–9674. 

143.   “Initiating Radical Cyclizations By H• Transfer From Transition Metals”, J. Hartung, M. E. Pulling, D. M. Smith, D. X. Yang, and J. R. Norton*, Tetrahedron 2008, 64, 11822-11830. 

142.  “Unusually Weak Metal-Hydrogen Bonds in HV(CO)4(P-P) and Their Effectiveness as H• Donors”, J. W. Choi, M. E. Pulling, D. M. Smith, J. R. Norton, J. Am. Chem. Soc. 2008; 130; 4250-4252.

141.  “Direct Measurement of the Rate of Interconversion  of Zirconaaziridine Enantiomers”, S. A. Cummings, J. A. Tunge, J. R. Norton, J. Am. Chem. Soc. 2008; 130; 4669-4679. 

140.  “Chain-Transfer Catalysis by Vanadium Complexes during Methyl Methacrylate Polymerization”, J. W. Choi, J. R. Norton, Inorg. Chim. Acta (Special Issue, Robert J. Angelici) 2008, 130, 4250–4252.  

139.  “Synthesis and Properties of Carboxy-Substituted Half-Sandwich Ruthenium Complexes with Chelating Bisphosphine Ligands (η5-C5H4CO2H)Ru(η2-L)X (X = I, H)”, A. P. Shaw, H. Guan, J. R. Norton, J. Organomet. Chem. 2008, 693, 1382-1388.

138. “Enantioselective Methylalumination of a-Olefins”, R. A. Petros, J. M. Camara, J. R. Norton, J. Organomet. Chem.(Special Issue, Gerhard Erker) 2007, 692, 4768-4773.

137. “Electron Exchange Involving a Sufur-Stabilized Ruthenium Radical Cation” A.P. Shaw, B.L. Ryland, J.R. Norton, D. Buccella, A. Muscatelli;  Inorg. Chem.; 2007, 46, 5805-5812.

136. “Tin-Free and Catalytic Radical Cyclizations” D. M. Smith, M.E. Pulling and J.R. Norton; J. Am. Chem. Soc.; 2007, 129, 770-771.

135.  "Kinetics of Hydrogen Atom Transfer from (C5H5)Cr(CO)3H to Various Olefins: Influence of Olefin Structure" Choi, J.; Tang, L.; Norton, J. R.; J. Am. Chem. Soc.; 2007; 129; 234-240

134. "Measurement of the Rate Constant for Hydroden Atom Abstraction from Methylisobutyryl Radical by (C5Ph5)Cr(CO)3 Radical" Tang, L.; Norton, J. R.;Macromolecules; 2006; 39; 8236-8240 

133. "Factors Affecting the Apparent Chain Transfer Rate Constants of Chromium Metalloradicals: Mechanistic Implications" Tang, L.; Norton, J. R.; Macromolecules; 2006; 39; 8229-8235.

132. "An Estimate of the Reduction Potential of B(C6F5)3 from Electrochemical Measurements on Related Mesityl Boranes" Cummings, S. A.; Iimura, M.; Harlan, C. J.; Kwaan, R. J.; Trieu, I. V.; Norton, J. R.; Bridgewater, B. M.; Jakle, F.; Sundararaman, A.; Tilset, M.; Organometallics; 2006; 25; 1565-1568.

131.  "Ruthenium-Catalyzed Ionic Hydrogenation of Aziridinium Cations"  Guan, H.; Saddoughi, S. A.; Shaw, A. P.; Norton, J. R.;  Organometallics; 2005; 24; 6358-6364.

130. "Ruthenium-Catalyzed Ionic Hydrogenation of Iminium Cations. Scope and Mechanism"
Guan, H.; Iimura, M.; Magee, M. P.; Norton, J. R.; Zhu, G.;  J. Am. Chem. Soc.; 2005; 127; 7805-7814

129. “Synthesis and Reactivity of Zirconaaziridines." Cummings, S.A.; Tunge, J.A.; Norton, J.R.  In New Aspects of Zirconium-Containing Organic Compounds; Marek, I., Ed. Topics in Organometallic Chemistry, Vol. 10; Springer-Verlag: Berlin Heidelberg, 2005, 1-39.

128. “Effectiveness in Catalyzing Carboalumination Can Be Inferred from the Rate of Dissociation of M/Al Dimers."  R.A. Petros and J.R. Norton*, Organometallics, 2004, 22, 5105-5107.

127. "The Effect of Steric Congestion on the Activity of Chromium and Molybdenum Metalloradicals as Chain Transfer Catalysts during MMA Polymerization." L. -H. Tang, J. R. Norton*, Macromolecules 2004, 37, 241-243.

126. "A Vibrational Study of the Diosmacyclobutene Complex Os2(CO)8211-C2H2):  The Use of Organometallic Complexes as Vibrational Models for Chemisorbed Ethyne." C. E. Anson, N. Sheppard, R. Pearman, J. R. Moss, P. Stößel, S. Koch, J. R. Norton*, Physical Chemistry Chemical Physics 2004, 5, 1070-1076.

125. "Inverse Temperature Dependence of Chain Transfer Rate Constant for a Chromium Metalloradical in Ploymerization of MMA." L. -H. Tang, J. R. Norton*, J. C. Edwards, Macromolecules 2003, 36, 9716-9720.

124. "Effect of Chelate Ring Size on the Rate of Hydride Transfer from CpRu(P-P)H (P-P = Chelating Diphosphine) to an Iminium Cation." H. -R. Guan, M. Iimura, M. P. Magee, J. R. Norton*, K. E. Janak, Organometallics 2003, 4084-4089.

123. "Kinetics and Thermodynamics of H• Transfer From (η5-C5R5)Cr(CO)3H (R = Ph, Me, H) to Methyl Methacrylate and Styrene." L. -H. Tang, E. T. Papish, G. P. Abramo, J. R. Norton,* M. -H. Baik, R. A. Friesner, A. Rapp¨·, J. Am. Chem. Soc. 2003, 125, 10093-10102.

122. "Asymmetric Synthesis of Silylated a-Amino Acid Esters through Dynamic Kinetic Resolution." J. -X. Chen, J. A. Tunge, J. R. Norton*, J. Org. Chem. 2002, 67, 4366-4369.

121."Indirect Determination of the Rate of Iron Uptake into the Apoprotein of the Ribonucleotide Reductase of E. coli." N. J. Umback, J. R. Norton, Biochemistry, 2002, 41, 3984-3990.

120."Protonation of Transition Metal Hydrides to Give Dihydrogen Complexes: Mechanistic Implications and Catalytic Applications." E.T. Papish, M.P. Magee, J.R. Norton. In Recent Advances in Hydride Chemistry; Poli, R., Ed.; Elsevier: New York, 2001; Chapter 2.

119. "Generation and Characterization of the Tris(pentafluorophenyl)borane Radical Anion." R.J. Kwaan, C.J. Harlan, J.R. Norton*, Organometallics, 2001, 20, 3818-3820.

118. "Stoichiometric, Catalytic and Enantioface-Selective Hydrogenation of C=N Bonds by an Ionic Mechanism." M. Magee, J. Norton*, J. Am. Chem. Soc., 2001, 123, 1778-1779.

117. "Rhenium Oxo Complexes of a Chelating Diyne Ligand. Synthesis and Study of the Kinetics of Protonation." Y. Han, C. J. Harlan, P. Strößl, J. R. Norton*, S. Miller, B. Bridgewater, Q. Xu, Inorg. Chem., 2001, 40, 2942-2952.

116. "Mechanism of Insertion of Carbodiimides into the Zr-­C Bonds Zirconaaziradines. Formation of a-Amino Amidines". J.A. Tunge, C. Czerwinski, D.A. Gately, J.R. Norton*, Organometallics, 2001, 20, 254-260.

115. "Protonation of CpW(CO)2(PMe3)H: Is the Metal or the Hydride the Kinetic Site". E.T. Papish, F. Rix, N. Spetseris, J.R. Norton*, R.D. Williams, J. Am. Chem. Soc., 2000, 49, 12235-12242.

114. "Aqua, Alcohol and Acetonitrile Adducts of Tris(perfluorophenyl)borane:Evaluation of Brønsted Acidity and Ligand Lability using Experimental and Computational Methods". C. Bergquist, B. M. Bridgewater, C. J. Harlan, J.R. Norton*, R. A. Friesner*, and G.Parkin*, J. Am. Chem. Soc., 2000, 122, 10581-10590.

113. "Trapping of Acetylene by a Zirconocene Terminal Imido Complex". J.R. Norton*, C.J. Harlan, J.A. Tunge, B.M. Bridgewater, Organometallics, 2000, 12, 2365-2372.

112. "Catalysis by C5Ph5Cr(CO)3• of Chain Transfer during the Free Radical Polymerization of Methyl Methacrylate". G. P. Abramo, J. R. Norton*, Macromolecules, 2000, 33, 2790-2792.

111. "Reaction of the Lewis Acids B(C6F5)3 and (AIMe2Cl)2 with Azairconacycles". C. J. Harlan, B. M. Bridgewater, T. Hascall, J. R. Norton*, Organometallics, 1999, 18, 3827-3834.

110. "The One-Electron Oxidation of an Azazirconacyclobutene in the Presence of B(C6F5)3". C.J. Harlan, T. Hascall, E. Fujita, J.R. Norton*, J. Am. Chem. Soc., 1999, 121, 7274-7275.

109. "Asymmetric Formation of a -Amino Acid Esters through Dynamic Kinetic Resolution. A Cyclic Carbonate as an Optically Active CO2 Synthon", J.A. Tunge, Daniel A. Gately, J.R. Norton*, J. Am. Chem. Soc., 1999, 121, 4520-4521.

108. "Isotope Effect on Hydrogen Atom Transfer From Transition Metals to Carbon", M.A. Rodkin, G.P. Abramo, K.E. Darula, D.L. Ramage, B.P. Santora, J.R. Norton*, Organometallics, 1999, 18, 1106-1109.

107. "[Os2(CO)8211-propene)] and Related Complexes as Vibrational Models for Alkenes Chemisorbed on Single-crystal Metal Surfaces.", C.E. Anson*, N. Sheppard, B.R. Bender, J.R. Norton, J. Am. Chem. Soc., 1999, 121, 529-534.

106. "Ethylene Ligand Structures of Os(CO)4(C2H4) and Os2(CO)8(C2H4) Determined by 1H NMR in Liquid Crystal Solvents", B.R. Bender, E.E. Burnell, R.T. Hembre, J.R. Norton*, Inorg. Chem. 1998, 37, 1720-1728.

105. "Evidence for a Ring Opening Preequilibrium in the Exchange Reactions of Diosmacyclobutanes", B.R. Bender, D.L. Ramage, J.R. Norton*, D.C. Wiser, A.K. Rappé, J. Am. Chem. Soc. 1997, 119, 5628-5637.

104. "Kinetics of Diosmacyclobutane Exchange Reactions", D.L. Ramage, D.C. Wiser, J.R. Norton*, J. Am. Chem. Soc. 1997, 119, 5618-5627.

103. "Kinetics and Mechanism of Alkyl Transfer from Organocobalt(III) to Nickel(I): Implications for the Synthesis of Acetyl Coenzyme A by CO Dehydrogenase", C.G. Riordan*, M.S. Ram, G.P.A. Yap, L. Liable-Sands, A.L. Rheingold, A. Marchaj, J.R. Norton, J. Am. Chem. Soc. 1997, 119, 1648-1655.

102. "Single-step Hydride Transfer from CpMo(CO)2(PPh3)H to Protonated Ketones", K.-T. Smith, M. Tilset, J.R. Norton*, Organometallics1996, 15, 4515-4520.

101. "Origin of Stereochemistry in the a-Amino Acid Esters and Amides Generated from Optically Active Zirconaaziridine Complexes", D.A. Gately and J.R. Norton*, J. Am. Chem. Soc. 1996, 118, 3479-3489.

100. "Kinetic Isotope Effects on M-to-N Proton Transfers", K.-T. Smith, M. Tilset, S.S. Kristjánsdóttir and J.R. Norton*, Inorg. Chem. 1995, 34, 6497-6504.

99. "Methyl/Phenyl Exchange between Palladium and a Phosphine Ligand. Consequences for Catalytic Coupling Reactions", D.K. Morita, J.K. Stille and J.R. Norton*, J. Am. Chem. Soc. 1995, 117, 8576-8581.

98. "Non-Metallocatalyzed Epoxidation of Chiral Unsaturated Lactams By Tertiary Amine N-Oxides", C.J. Andres, N. Spetseris, J.R. Norton and A.I. Meyers, Tetrahedron Letters 1995, 36, #10, 1613-1616.

97. "The Reaction of 1,3 Butadiene and Allene with a Diosmacyclobutane", N. Spetseris, C.D. Rithner and J.R. Norton, Organometallics 1995, 14, 603.

96. "The Insertion of Isocyanates, CO2, and Ethylene Carbonate into the Zr-C and Zr-N Bonds of Imine Complexes. The Construction of Chiral Centers Like Those in a-Amino Acids", D.A. Gately, P.A. Goodson and J.R. Norton*, J. Am. Chem. Soc. 1995, 117, 986-996.

95. "Mechanism of Transition-Metal-Mediated Nitrogen Fixation: Where Does the Third Proton Go?", P.S. Wagenknecht and J.R. Norton*, J. Am. Chem. Soc. 1995, 117, 1841-1842.

94. "Retention of Stereochemistry in the Formation and Fragmentation of Diosmacyclobutanes, and Other Evidence Against a Diradical Mechanism", R.T. Hembre, D.L. Ramage, C.P. Scott and J.R. Norton*, Organometallics1994, 13, 2995-3001.

93. "[(η2-C2H4)Os(CO)4] as a Vibrational Model for Type I' Ethene Chemisorbed as a Metallacyclopropane on Metal Surfaces", C.E. Anson, N. Sheppard*, D.B. Powell, B.R. Bender and J.R. Norton, J. Chem. Soc., Faraday Trans. 1994, 90, 1449-1454.

92. "Slow Proton Transfer Reactions in Organometallic and Bioinorganic Chemistry", K.W. Kramarz and J.R. Norton, Prog. Inorg. Chem. 1994, 42, 1.

91. "Assignments of the Infrared and Raman Spectra of the Os22-CHCH3) Group of [µ2-CHCH3) Os2 (CO)8] and of their d1 and d4 Isotopologues as Models for the Spectrum of such Ethylidene Groups on Metal Surfaces", C.E. Anson, N. Sheppard*, D.B. Powell, J.R. Norton*, W. Fischer, R.L. Keiter, B.F.G. Johnson, J. Lewis, A.K. Bhattacharrya, S.A.R. Knox, and M.L. Turner, J. Am. Chem. Soc. 1994, 116, 3058-3062.

90. "Reaction of µ-Oxobis[(trifluoromethanesulfanato)(phenyl)iodine(III)] with Group 14 Propargyl Derivatives and a Propargyl Ether", D.A. Gately, T.A. Luther, J.R. Norton*, M.M. Miller, and O.P. Anderson, J. Org. Chem. 1992, 57, 6496-6502.

89. "The Structure of Os(CO)4(C2H4), an Osmacyclopropane", B.R. Bender, J.R. Norton*, M.M. Miller, O.P. Anderson, and A.K. Rappé*, Organometallics 1992, 11, 3427-3434.

88. "The Protonation of a Bridging Oxo Ligand is Slow", J.M. Carroll, and J.R. Norton*, J. Am. Chem. Soc. 1992, 114, 8744-8745. [corrected, J. Am. Chem. Soc. 1993, 115, 12639]

87. "Hydride Transfer Reactions of Transition Metal Hydrides. Ionic Hydrogenation of Aldehydes and Ketones, and Structural Characterization of an Alcohol Complex", J.-S. Song, D.J. Szalda, R.M. Bullock*, C.J. Lawrie, M.A. Rodkin, and J.R. Norton*, Angew. Chem. Int. Ed. Engl. 1992, 31, 1233.

86. "Approach to Equilibrium after Dilution of a monomer/Dimer Mixture. Measurement of the Rate Constant for Dissociation of Trityl Dimer by Stopped-Flow Methods", S.S. Kristjánsdóttir, A.E. Moody, and J.R. Norton*, Int. J. Chem. Kinetics 1992, 24, 895.

85. "Alpha vs. Beta Hydrogen Elimination in the Formation of Propene from an Osmacyclobutane", W. Fischer, R.T. Hembre, D.R. Sidler, and J.R. Norton, Inorg. Chim. Acta 1992, 198-200, 57.

84. "Synthesis of Dimethylaminoalkyl Zirconocene Complexes and Their Dynamic Behavior", K. Plößl, J.R. Norton*, J.G. Davidson, and E.K. Barefield*, Organometallics 1992, 11, 534.

83. "Synthesis and Structure of Two Organozirconocenes with a Nitrogen Substituents", T.V. Lubben, K. Plöbl, J.R. Norton*, M.M. Miller, and O.P. Anderson, Organometallics 1992, 11, 122.

82. "Acidity of Hydrido Transition Metal Complexes in Solution", S.S. Kristjánsdóttir and J.R. Norton*, Transition Metal Hydrides; Dedieu, A., Ed.; VCH: New York, 1992, Chapter 9.

81. "Kinetic and Thermodynamic Acidity of Hydrido Transition-Metal Complexes. 9. A Sterically Hindered Cationic Hydride, [H4Re(PMe2Ph)4]+", S.S. Kristjánsdóttir, A.J. Loendorf, and J.R. Norton*, Inorg. Chem. 1991, 30, 4470.

80. "Hydrogen-Atom Transfer Reactions of Transition-Metal Hydrides", D.C. Eisenberg and J.R. Norton, Isr. J. Chem. 1991, 31, 55.

79. "A Single Crystal Neutron Diffraction Study of (μ–η11–C2H4)Os2(CO)8, A Model for One Type of Chemisorbed Ethylene", O.P Anderson, B.R. Bender, J.R. Norton*, A.C. Larson*, and P.J. Vergamini, Organometallics1991, 10, 3145.

78. "Mechanism of Assembly of the Tyrosyl Radical - Dinuclear Iron Cofactor of Ribonucleotide Reductase", J.M. Bollinger, D.E. Edmondson, B.H. Huynh, J. Filley, J.R. Norton, and J. Stubbe, Science 1991, 253, 292.

77. "The Absence of Hydrogen Bonding between HCo(CO)4 and Nitrogen or Oxygen Bases. An IR and Raman Study", S.S. Kristjánsdóttir, J.R. Norton*, A. Moroz, R.L. Sweany*, and S.L. Whittenburg, Organometallics1991, 10, 2357.

76. "Relative Rates of H• Transfer from Transition-Metal Hydrides to Trityl Radicals", D.C. Eisenberg, C.J.C. Lawrie, A.E. Moody and J.R. Norton*, J. Am. Chem. Soc. 1991, 113, 4888.

75. "The Agreement of Proton Transfer Cross Reaction Rates between Transition Metals with Those Predicted by Marcus Theory", S.S. Kristjánsdóttir, and J.R. Norton*, J. Am. Chem. Soc.1991, 113, 4366.

74. "The Photochemistry of Dinuclear Osmium Carbonyl Complexes; Characterization of Os2(CO)8 Using Matrix Isolation", A. Haynes, M. Poliakoff, J.J. Turner, B. Bender and J.R. Norton, J. Organomet. Chem. 1990, 383, 497.

73. "Kinetic and Thermodynamic Acidity of Hydrido Transition-Metal Complexes. 6. Interstitial Hydrides", R.T. Weberg and J.R. Norton*, J.Am. Chem. Soc. 1990, 112, 1105.

72. "UV Photoelectron Spectra and Electronic Structure of 1,2-Diosmacyclopropane and 1,2-Diosmacyclobutane Complexes", B.R. Bender, R. Bertoncello, M.R. Burke, M. Casarin, G. Granozzi, J. Takats, and J.R. Norton*, Organometallics 1989,8, 1777.

71. "Intramolecular Hydrogen Exchange Among the Coordinated Methane Fragments of Cp2W(H)CH3", C.L. Headford, S. Kegley, R.M. Bullock, K. M. Hennessy, and J.R. Norton*, J. Am. Chem. Soc. 1989, 111, 3897.

70. "[Os2(CO)822-C2H4)] as a Vibrational Model for 1,2-di-s Chemisorbed Ethylene on Metal Surfaces", C.E. Anson, B.F.G. Johnson, J. Lewis, D.B. Powell, N. Sheppard, A.K. Bhattacharyya, B.R. Bender, R.M. Bullock, R.T. Hembre, and J.R. Norton*, J. Chem. Soc. Chem. Commun. 1989, 11, 703.

69. "Synthesis of Os2(CO)8(μ-CHCH3) from a Geminal Ditriflate and its Reversible Carbonylation to a Ketene-bridged Diosmacycle", R.M. Bullock, R.T. Hembre, J.R. Norton*, J. Am. Chem. Soc. 1988, 110, 7868.

68. "The Hydroformylation of Coordinated Acetone", S.A. Matchett, J.R. Norton*, and O.P. Anderson, Organometallics 1988,7, 2228.

67. "Kinetic and Thermodynamic Acidity of Hydrido Transition-Metal Complexes. 5. Sensitivity of Thermodynamic Acidity to Ligand Variation and Hydride Bonding Modes", S.S. Kristjánsdóttir, A.E. Moody, R.T. Weberg, and J.R. Norton*, Organometallics 1988, 7, 1983.

66. "The Formation of Dinuclear Complexes from Mononuclear Hydrides", R.T. Edidin, K.M. Hennessy, A.E. Moody, S.J. Okrasinski, J.R. Norton*, New J. Chem. 1988, 12, 475.

65. "The Formation of the Hydrogen-Transition Metal Bond: 1.10.8 By Hydrogen Transfer from Solvent or Coordinated Group to the Metal", J.R. Norton, Inorganic Reactions and Methods, Vol. 2, Verlag Chemie, 1988, 226.

64. "The Formation of the Hydrogen-Transition Metal Bond: 1.10.7 By Reactions of Metal Complexes with Complex Hydrides", J.R. Norton, Inorganic Reactions and Methods, Vol. 2, Verlag Chemie, 1988, 220.

63. "The Formation of the Hydrogen-Transition Metal Bond: 1.10.6 By Protonation Reactions of Metal Complexes", J.R. Norton, Inorganic Reactions and Methods, Vol. 2, Verlag Chemie, 1988, 204.

62. "The Conversion of Olefins to Ditriflates by μ-Oxobis[trifluoromethanesulfonato(phenyl)iodine]", R.T. Hembre, C.P. Scott, J.R. Norton*, J. Org. Chem. 1987, 52, 3650.

61. "Kinetic and Thermodynamic Acidity of Hydrido Transition-Metal Complexes. 4. Kinetic Acidities Toward Aniline and Their Use in Identifying Proton Transfer Mechanisms", R.T. Edidin, J.M. Sullivan, and J.R. Norton*, J. Am. Chem. Soc. 1987, 109, 3945.

60. 'The Reversible Stereospecific Extrusion of Ethylene from a 1,2-Diosmacyclobutane. Determination of Stereochemistry by Liquid Crystal NMR'', R. T. Hembre, C. P. Scott, J. R. Norton*, J. Am. Chem. Soc.1987, 109, 3468.

59. Principles and Applications of Organotransition Metal Chemistry, J.P. Collman, L.S. Hegedus, J.R. Norton, R.G. Finke, University Science Books: Mill Valley, California, 1987.

58. "Kinetic and Thermodynamic Acidity of Hydrido Transition-Metal Complexes. 3. Thermodynamic Acidity of Common Mononuclear Carbonyl Hydrides", E.J. Moore, J.M. Sullivan, and J.R. Norton*, J. Am. Chem. Soc. 1986, 108, 2257.

57. "A Radical Chain Mechanism for Dinuclear C-H Bond Formation", R.T. Edidin and J.R. Norton*, J. Am. Chem. Soc. 1986, 108, 948.

56. "Mechanism of the Reaction of a Solvated Rhenium Acyl Complex with Neutral Transition-Metal Hydrides. Relative Nucleophilicity of Such Hydrides", B.D. Martin, K.E. Warner, and J.R. Norton*, J. Am. Chem. Soc. 1986, 108, 33.

55. "Nucleophilic Attack on η2-Acetyl Ligands. Structure of a Bridging η2-Acetone Complex", B.D. Martin, S.A. Matchett, J.R. Norton*, and O.P. Anderson*, J. Am. Chem. Soc. 1985, 107, 7952.

54. "Intermolecular Formation of C-H Bonds: Application to the Synthesis Heterobimetallic Complexes", K.E. Warner and J.R. Norton*, Organometallics, 1985, 4, 2150.

53. "The Mechanisms of the Elimination Reactions of Os(CO)4(H)R and Os(CO)4R2", W.J. Carter, S.J. Okrasinski, and J.R. Norton*, Organometallics 1985, 4, 1376.

52. "Synthesis and Solution Properties of the Heterobimetallic Complexes Cp2ZrMe(μ-OC)Mo(CO)2Cp(M = Cr, Mo, W) and of their Carbonylation Derivatives. Structure of Cp2ZrMe(m-OC)Mo(CO)2Cp", B. Longato, B.D. Martin, J.R. Norton*, and O.P. Anderson, Inorg. Chem.1985, 24, 1389.

51. "Hydrogen Exchange Between the Methyl and Hydride Ligands of Cp2W(H)CH3 Prior to Methane Elimination", R.M. Bullock, C.E.L. Headford, S.E. Kegley, and J.R. Norton*, J. Am. Chem. Soc. 1985, 107, 727.

50. "Mechanism of Acetylene and Olefin Insertion into Palladium-Carbon s Bonds", E.G. Samsel and J.R. Norton*, J. Am. Chem. Soc. 1984, 106, 5505.

49. "The Synthesis, Structure and Reactions of Dinuclear Compounds Containing Early and Late Transition Metals", R.T. Edidin, B. Longato, B.D. Martin, S.A. Matchett, and J.R. Norton*, Organometallic Compounds: Synthesis, Structure, and Theory, Shapiro, B.L., editor, Texas A and M University Press, 1983, pp. 260.

48. "Synthesis and Structure of Diosmacycloalkanes. Reversible Addition of Ethylene to a Methylene-Bridged Dimer", K.M. Motyl, J.R. Norton*, C.K. Schauer, and O.P. Anderson*, J. Am. Chem. Soc. 1982, 104, 7325.

47. "Dinuclear Elimination As a Route to Unusual Bridging Carbonyls and Acetyls in Heterobimetallic Complexes", J.A. Marsella, J.C. Huffman, K.G. Caulton, B. Longato, and J.R. Norton*, J. Am. Chem. Soc. 1982, 104, 6360.

46. "Mononuclear Hydrido Alkyl Carbonyl Complexes of Osmium and Their Polynuclear Derivatives", W.J. Carter, J.W. Kelland, S.J. Okrasinski, K.E. Warner, and J.R. Norton*, Inorg. Chem. 1982, 21, 3955.

45. "Proton-Transfer Reactions in Organometallic Chemistry", R.F. Jordan and J.R. Norton*, ACS Symposium Series,1982, 198, 403.

44. "Evidence for Tilted Ground State Structures and Fluxionality in Co3(CO)9CCHR+", R.T. Edidin, J.R. Norton*, and K. Mislow*, Organometallics 1982, 1, 56l.

43. "Kinetic and Thermodynamic Acidity of Hydrido Transition-Metal Complexes. l. Periodic Trends in Group 6 Complexes and Substituent Effects in Osmium Complexes", R.F. Jordan, and J.R. Norton*, J. Am. Chem. Soc.l982, 104, l255.

42. "Palladium-Catalyzed Cyclocarbonylation of Acetylenic Alcohols to Methylene Lactones. Scope and Synthesis of Appropriate Substrates," T.F. Murray, E.G. Samsel, V. Varma and J.R. Norton*, J. Am. Chem. Soc.1981, 103, 7520.

41. "A Bridging Acetyl Group from the Reaction of a Dinuclear Methyl Complex with Carbon Monoxide", B. Longato, J.R. Norton*, J.C. Huffman, J.A. Marsella, and K.G. Caulton*, J. Am. Chem. Soc. 1981, 103, 209.

40. "Scope of the Pd-Catalyzed Cyclocarbonylation of Unsaturated Alcohols to α-Substituted Lactones", J.R. Norton*, Preprints, Div. of Petr. Chem., Am. Chem. Soc. 1980, 25, 368.

39. "13C NMR Relaxation Mechanisms in Methyl-Transition Metal Compounds", R.F. Jordan and J.R. Norton*, J. Am. Chem. Soc. 1979, 101, 4853.

38. "Iron-Sulphur Clusters with Rigid Chiral Frameworks", R.T. Edidin, L.A. Zyzyck, and J.R. Norton*, J. Chem. Soc., Chem. Commun.1979, 580.

37. "The Design and Mechanism of Palladium Catalysts for Synthesis of Methylene Lactones by Cyclocarbonylation of Acetylenic Alcohols", T.F. Murray and J.R. Norton*, J. Am. Chem. Soc. 1979, 101, 4107.

36. "Organometallic Elimination Mechanisms: Studies on Osmium Alkyls and Hydrides", J.R. Norton*, Accounts of Chemical Research1979, 12, 139.

35. "Osmium Hydridoalkyls and their Elimination Mechanisms", J.R. Norton*, W.J. Carter, J.W. Kelland, and S.J. Okrasinski, Advances in Chemistry Series 1978, 167, 170.

34. "Carbon-13 Nuclear Magnetic Resonance Spectra of Polynuclear Carbonyls of Cobalt and Rhodium", J. Evans, B.F.G. Johnson, J. Lewis and J.R. Norton, J. Chem. Soc., Dalton Trans. 1978, 626.

33. "Some Reactions of Polynuclear Osmium Carbonyl Alkyls", J.W. Kelland and J.R. Norton*, J. Organomet. Chem. 1978, 149, 185.

32. "C-13 Relaxation Mechanisms in Transition-Metal Methyl Complexes: High Barriers to Rotation About Metal-Carbon s Bonds", R.F. Jordan, E. Tsang and J.R. Norton*, J. Organomet. Chem. 1978, 149, C53.

31. "Cyclocarbonylation of 2-exo-Ethynyl-7-syn-norbornanol to an α-Methylene-δ-Lactone", T.F. Murray, V. Varma and J.R. Norton*, J. Org. Chem. 1978, 43, 353.

30. "Interactions in Metal Clusters. 3. Racemization Barriers and Reversible Hydrogen Addition of a Series of Chiral Clusters", A. Agapiou, R.F. Jordan, L.A. Zyzyck, and J.R. Norton*, J. Organomet. Chem.1977, 141, C35.

29. "Mechanism of the Palladium-Catalyzed Synthesis of α-Methylene Lactones from Carbon Monoxide and Acetylenic Alcohols", T.F. Murray, V. Varma, and J.R. Norton*, J. Am. Chem. Soc. 1977, 99, 8085.

28. "Metal Clusters in Catalysis", J.R. Norton*, in Advances in Homogeneous Catalysis, Vol. l, R. Ugo and M. Tsutsui, editors, Plenum, New York, 1977, pp. 99.

27. "Barrier to Racemization of the Framework of a Chiral Polynuclear Cation", A. Agapiou, S.E. Pedersen, L.A. Zyzyck and J.R. Norton*, Chem. Commun. 1977, 393.

26. ''Mechanism of Reductive Elimination. 3. Methyl Radical Elimination from cis-Dimethyltetracarbonylosmium'', J. Evans, S.J. Okrasinski, A.J. Pribula and J.R. Norton*, J. Am. Chem. Soc. 1977, 99, 5835.

25. "Mechanism of Reductive Elimination. 2. Control of Dinuclear vs. Mono-nuclear Elimination of Methane from cis- Hydridomethyltetracarbonyl-osmium", S.J. Okrasinski and J.R. Norton*, J. Am. Chem. Soc. 1977, 295.

24. "Ethynyl Alcohol Precursors to Methylene Lactones", T.F. Murray, V. Varma and J.R. Norton*, Chem. Commun. 1976, 907.

23. "Frontier Areas Between Homogeneous and Heterogeneous Catalysis", edited by J.R. Norton and J.M. Basset, in Proceedings of the First International Workshop on Fundamental Research in Homogeneous Catalysis, Palermo, Italy, 1976.

22. "Synthesis of Di- and Trinuclear Methyl Osmium Complexes via cis-Hydridomethyltetracarbonylosmium'', J. Evans, S.J. Okrasinski, A.J. Pribula and J.R. Norton*, J. Am. Chem. Soc. 1976, 98, 4000.

21. "Catalysis by Polynuclear Complexes: A Bridge Between Homogeneous and Heterogeneous Catalysis", J.R. Norton*, Preprints, Division of Petroleum Chemistry, American Chemical Society 1976, 21, 343.

20. "Carbonylnitrosylchlororhenium Compounds", G. Dolcetti and J.R. Norton*, Inorganic Synthesis, Vol XVI, McGraw Hill, 1976, 35.

19. "Decacarbonyldi-μ-Nitrosyl-Trimetal Compounds", J.R. Norton* and G. Dolcetti, Inorganic Synthesis, Vol XVI, McGraw Hill, 1976, 39.

18. "Catalytic Synthesis of α-Methylene Lactones by Carbonylation of Acetylenic Alcohols", J.R. Norton*, K.E. Shenton and J. Schwartz, Tetrahedron Lett. 1975, 51.

17. "13C NMR Spectra of Some Carbon Monoxide 13C-Labelled Derivatives of Platinum(II)", W.J. Cherwinski, B.F.G. Johnson, J. Lewis and J.R. Norton, J. Chem. Soc., Dalton Trans. 1975, 1156.

16. "Workshop on Fundamental Research in Homogeneous Catalysis as Related to U.S. Energy Problems", J.R. Norton, editor, Stanford, 1974.

15. "Chemical Shifts of Carbon Atoms Bound to Transition Metals", J. Evans and J.R. Norton*, Inorg. Chem. 1974, 13, 3042.

14. "Mechanisms of Reductive Elimination. I. Dinuclear Elimination of Hydrogen from cis-Dihydridotetracarbonylosmium", J. Evans and J.R. Norton*, J. Am. Chem. Soc. 1974, 96, 7577.

13. "Interactions in Metal Clusters. I. Acceleration of Substitution by Prior Substitution at Adjacent Metal Centers", K.J. Karel and J.R. Norton*, J. Am. Chem. Soc. 1974, 96, 6812.

12. "Applications of Lanthanide Shift Reagents to 13C and 1H NMR, B.F.G. Johnson, J. Lewis, P. McArdle and J.R. Norton, J. Chem. Soc., Dalton Trans. 1974, 1253.

11. "Structure and Dynamical Properties of Rh4(CO)12 in Solution: 13C Nuclear Magnetic Resonance Study", J. Evans, B.F.G. Johnson, J. Lewis, J.R. Norton and F.A. Cotton, Chem. Commun. 1973, 807.

10. "Kinetics of Tertiary Phosphine Substitution on Di-μ-nitrosyldecacar-bonyltriruthenium", J.R. Norton and J.P. Collman, Inorg. Chem. 1973, 12, 476.

9. "Rhenium Nitrosyl Carbonyl Complexes", J.R. Norton* and G. Dolcetti, Inorg. Chem. 1973, 12, 485.

8. "Variable Temperature 13C Nuclear Magnetic Resonance of Dicyclopenta-dienyltricarbonyldirhodium", J. Evans, B.F.G. Johnson, J. Lewis and J.R. Norton, Chem. Commun. 1973, 79.

7. "Synthesis of H3Ru3(CO)9CCH3, a Ruthenium Ethylidyne Complex", A.J. Canty, B.F.G. Johnson, J. Lewis and J.R. Norton, Chem. Commun. 1972, 1331.

6. "Contact Effects in NMR Spectra with Lanthanide Shift Reagents", B.F.G. Johnson, J. Lewis, P. McArdle and J.R. Norton, Chem. Commun.1972, 535.

5. "Resin-Bound Transition Metal Complexes", J.P. Collman, L.S. Hegedus, M.P. Cooke, J.R. Norton, G. Dolcetti and D.N. Marquardt, J. Am. Chem. Soc. 1972, 94, 1789.

4. "The Preparation and Structure of Ruthenium and Osmium Carbonyl Clusters Containing Double Nitrosyl Bridges", J.R. Norton, J.P. Collman, G. Dolcetti and W.T. Robinson, Inorg. Chem. 1972, 11, 382.

3. "Electron Spin Resonance Studies of Substituent Effects. III. Electron Withdrawal by Group IV and Group VI Elements", E.T. Strom and J.R. Norton, J. Am. Chem. Soc. 1970, 92, 2327.

2. "A Novel Nitrosyl-Substituted Metal Carbonyl Cluster", J.R. Norton, D. Valentine and J.P. Collman, J. Am. Chem. Soc. 1969, 91, 7537.

1. "Benzene-Induced Nuclear Magnetic Resonance and Dipole Moment Shifts of Five-Membered Rings Containing Heteroatoms", E.T. Strom, B.S. Snowden, H.C. Custard, D.E. Woessner and J.R. Norton, J. Org. Chem.1968, 33, 2555.