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Publications

 

24. Cyclopropenimine-Catalyzed Enantioselective Mannich Reactions of t-Butyl Glycinates with N-Boc-Imines. Bandar, J. S.; Lambert, T. H. J. Am. Chem. Soc. 2013, 135, in press.

multicatalysis

23. Aminocyclopropenium Ions: Synthesis, Properties, and Applications. Bandar, J. S.; Lambert, T. H. Synthesis, 2013, in press.

multicatalysis

22. Cyclopropenone Catalyzed Substitution of Alcohols with Mesylate Ion. Nacsa, E. D.; Lambert, T. H. Org. Lett. 2013, 15, 38-41 .

multicatalysis

21. Diphenylcyclopropenone. Nacsa, E. D.; Lambert, T. H. Encyclopedia of Reagents for Organic Synthesis 2013. (DOI: 10.1002/047084289X.rn01532).

20. Organocatalytic Carbonyl-Olefin Metathesis. Griffith, A. K.; Vanos, C. M.; Lambert, T. H. J. Am. Chem. Soc. 2012, 134, 18581-18584. Highlighted in Angew. Chem. Int. Ed. 2013, 52, 4524.

multicatalysis

19. Enantioselective Brønsted Base Catalysis with Chiral Cyclopropenimines. Bandar, J. S.; Lambert, T. H. J. Am. Chem. Soc. 2012, 134, 5552-5555. Featured in C&EN, April 2, 2012.

multicatalysis

18. Development of a Catalytic Platform for Nucleophilic Substitution: Cyclopropenone Catalyzed Chlorodehydration of Alcohols. Vanos, C. M.; Lambert, T. H. Angew. Chem. Int. Ed. 2011, 50, 12222-12226.

multicatalysis

17. Demonstration of the Facile Reversibility of Fulvene Formation. Bandar, J. S.; Coscia, R. W.; Lambert, T. H. Tetrahedron, 2011, 67, 4364-4370. This article is part of a special Symposium-in-Print issue in honor of Prof. Dean Toste winning the Tetrahedron Young Investigator Award.

multicatalysis

16. Cyclopropenium-Activated Cyclodehydration of Diols. Kelly, B. D.; Lambert, T. H. Org. Lett., 2011, 13, 740-743.

multicatalysis

15. Tropylium Ion Mediated α-Cyanation of Amines. Allen, J. M.; Lambert, T. H. J. Am. Chem. Soc., 2011, 133, 1260-1262.

multicatalysis

14. Cyclopropenium-Activated Beckmann Rearrangement. Catalysis Versus Self-Propagation in Reported Organocatalytic Beckmann Rearrangements. Vanos, C. M.; Lambert, T. H. Chemical Science, 2010, 1, 705-708.

multicatalysis

13. Multicatalysis: Advancing Synthetic Efficiency and Inspiring Discovery. Ambrosini, L. M.; Lambert, T. H. Chem. Cat. Chem. 2010, 2, 1373-1380.

multicatalysis

12. Nucleophilic Acyl Subsitution via Aromatic Cation Activation of Carboxylic Acids: Rapid Generation of Acid Chlorides Under Mild Conditions. Hardee, D. J.; Kovalchuke, L.; Lambert, T. H. J. Am. Chem. Soc. 2010, 132, 5002-5003.

cyclopropanation

11. Total Synthesis of the Tylophora Alkaloids Rusplinone, 13aa-Secoantofine, and Antofine using a Multicatalytic Oxidative Aminochlorocarbonylation / Friedel-Crafts Reaction. Ambrosini, L. A.; Cernak, T. A.; Lambert, T. H. Tetrahedron 2010, 66, 4882-4887. This article was published as part of a special Symposium-in-Print issue in honor of Prof. Brian Stoltz winning the Tetrahedron Young Investigator Award.

cyclopropanation

10. Development of Oxidative Formylation and Ketonylation Reactions. Ambrosini, L. A.; Cernak, T. A.; Lambert, T. H. Synthesis--Featured Article 2010, 870-881.

cyclopropanation

9. Aromatic Cation Activation of Alcohols: Conversion to Alkyl Chlorides Using Dichlorodiphenylcyclopropene. Kelly, B. D.; Lambert, T. H. J. Am. Chem. Soc. 2009, 131, 13930-13931.

cyclopropanation

8. Leaving Group Potential of a Substituted Cyclopentadienyl Anion Towards Oxidative Addition. Fisher, E. L; Lambert, T. H. Org. Lett 2009, 11, 4108-4110.

7. Lanthanum(III) Triflate-Catalyzed Cyclopropanation via Intramolecular Methylene Transfer. Hardee, D. J.; Lambert, T. H. J. Am. Chem. Soc. 2009, 131, 7536-7537.

cyclopropanation

6. Multicatalytic Synthesis of Complex Tetrahydrofurans Involving Bismuth(III) Triflate-Catalyzed Intramolecular Hydroalkoxylation of Unactivated Olefins. Kelly, B. D.; Allen, J. M.; Tundel, R. E.; Lambert, T. H. Org. Lett. 2009, 11, 1381-1383.

5. Multicatalytic Synthesis of a-Pyrrolidinyl Ketones via a Tandem Palladium(II)/In(III)-Catalyzed Aminochlorocarbonylation/Friedel-Crafts Acylation Reaction. Cernak, T. A.; Lambert T. H. J. Am. Chem. Soc. 2009, 131, 3124-3125.

4. Development of a Formal [4+1] Cycloaddition: Pd(OAc)2-Catalyzed Intramolecular Cyclopropanation of 1,3-Dienyl b-Keto Esters and MgI2-Promoted Vinylcyclopropane-Cyclopentene Rearrangement. Coscia, R. W.; Lambert, T. H. J. Am. Chem. Soc. 2009, 131, 2496-2498.

Doctoral and Postdoctoral

3. Total Synthesis of UCS1025A. Lambert T. H.; Danishefsky, S. J. J. Am. Chem. Soc. 2006, 128, 426.

2. Olefin Cross-Metathesis: A Powerful Tool for Constructing Vaccines Composed of Multimeric Antigens. Wan, Q.; Cho, Y. S.; Lambert, T. H.; Danishefsky, S. J. J. Carbohydrate Chem. 2005, 24, 425.

1. Development of a New Lewis Acid-Catalyzed [3,3]-Sigmatropic Rearrangement: The Allenoate-Claisen Rearrangement. Lambert, T. H.; MacMillan, D. W. C. J. Am. Chem. Soc. 2002, 124, 13646.

 

TRISTAN H. LAMBERT Department of Chemistry, Columbia University 3000 Broadway New York, NY 10027 [email protected] 212.854.1438..