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Modern Molecular Photochemistry Chapter 7 |
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7.
Theoretical Organic Photochemistry
7.1 A Qualitative Theory of Organic Photoreactions
7.2 The Principle of Maximum Positive Orbital
Overlap
7.3 Orbital Interactions
7.4 Orbital and State Correlation Diagrams
7.5 The Construction of Electron Orbital and
State Coordination Diagrams for a Selected Reaction Coordinate
7.6 Typical State Correlation Diagrams for
Concerted Photochemical Pericyclic Reactions
7.7 State Correlation Diagrams for Photoreactions
Involving Diradical Intermediates
7.8 Typical State Correlation Diagrams for
Non-Concerted Photoreactions: Reactions Involving Intermediates (Diradicals
and Zwitterions)
7.9 State Correlation Diagrams for a-Cleavage
of Ketones
7.10 A Standard Set of Primary Photoreactions
for pi,pi* and n,pi* States
7.11 Conclusion: Energy Surfaces as Reaction
Graphs
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